tert-Butyldimethylsilyl chloride → 3,5-Bis(tert-butyldimethylsilyloxy)benzaldehyde

HRID 658763

Reaction equation

HRID 658763 reaction equation
[OH:1][C:2]1[CH:3]=[C:4]([CH:7]=[C:8]([OH:10])[CH:9]=1)[CH:5]=[O:6].[C:11]([Si:15](Cl)([CH3:17])[CH3:16])([CH3:14])([CH3:13])[CH3:12]>>[Si:15]([O:1][C:2]1[CH:3]=[C:4]([CH:7]=[C:8]([O:10][Si:15]([C:11]([CH3:14])([CH3:13])[CH3:12])([CH3:17])[CH3:16])[CH:9]=1)[CH:5]=[O:6])([C:11]([CH3:14])([CH3:13])[CH3:12])([CH3:17])[CH3:16]

Participants

3

Reactant 2

HCID 28928tert-Butyldimethylsilyl chlorideHCID 943653,5-Dihydroxybenzaldehyde

Product 1

HCID 109155453,5-Bis(tert-butyldimethylsilyloxy)benzaldehydeYield 100%

Procedure

Prepared as in Example 12-1c from 3,5-dihydroxybenzaldehyde and tert-butylchlorodimethylsilane. Yield 100%, yellowish liquid. MS 267 (MH+).

Sources & evidence

ORD record
ord-4b3ce7b7e65e4d2a88e91f7ac0651156
Source dataset
uspto-grants-2011_12
Patent number
US08076491B2

Linked notes

Loading…