Pyridine → 6,6-Ethylenedioxy-2-methyl-2-(4'-oxobutyl)-oxepane

Reaction equation

[CH2:1]1[O:2][C:3]2([CH2:4][CH2:5][CH2:6][C:7]([CH3:10])([CH2:11][CH2:12][CH2:13][CH2:14][OH:15])[O:8][CH2:9]2)[O:16][CH2:17]1.[CH2:38]([Cl:39])[Cl:40].[O:24]=[Cr:25](=[O:26])=[O:27].[O:34]=[Cr:35](=[O:36])=[O:37].[cH:18]1[cH:19][cH:20][n:21][cH:22][cH:23]1.[cH:28]1[cH:29][cH:30][n:31][cH:32][cH:33]1>>[CH2:1]1[O:2][C:3]2([CH2:4][CH2:5][CH2:6][C:7]([CH3:10])([CH2:11][CH2:12][CH2:13][CH:14]=[O:15])[O:8][CH2:9]2)[O:16][CH2:17]1

Participants

Reactant 4

HCID 1049Pyridine2×

HCID 6344Dichloromethane

HCID 14915Chromium Trioxide2×

HCID 131881856,6-Ethylenedioxy-2-(4'-hydroxybutyl)-2-methyloxepane

Product 1

HCID 131881866,6-Ethylenedioxy-2-methyl-2-(4'-oxobutyl)-oxepane

Sources & evidence

ORD record: ord-7532be0daa0b4a198b17d3f823ba4d87
Source dataset: Training data from https://doi.org/10.1039/C8SC04228D (3/10)
DOI: 10.1039/C8SC04228D

Reaction notes

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