Bromide ion → 1-Bromo-3-triphenylmethoxy-trans-1-decene

HRID 67025

Reaction equation

HRID 67025 reaction equation
[C:1]1([C:7]([C:25]2[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=2)([C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=2)[O:8][CH:9]([CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])[C:10]#[CH:11])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(BC(C(C)C)C)(C(C)C)C.[Br-:42]>>[Br:42]/[CH:11]=[CH:10]/[CH:9]([O:8][C:7]([C:1]1[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1)([C:19]1[CH:20]=[CH:21][CH:22]=[CH:23][CH:24]=1)[C:25]1[CH:26]=[CH:27][CH:28]=[CH:29][CH:30]=1)[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]

Participants

4

Reactant 3

HCID 259Bromide ionHCID 192733Bis(1,2-dimethylpropyl)boraneHCID 204655353-Triphenylmethoxy-1-decyne

Product 1

HCID 204656311-Bromo-3-triphenylmethoxy-trans-1-decene

Procedure

Treatment of 3-triphenylmethoxy-1-decyne (Example 129) with disiamylborane and the bromide by the procedure described in Example 1173 is productive of the title compound.

Sources & evidence

ORD record
ord-3a8f39dadf9d4b60a1e83258cc1ccea6
Source dataset
uspto-grants-1982_08
Patent number
US04343949

Linked notes

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