HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ammonia → 5-Benzylidenehydantoin
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ammonia | HCID 222 | — |
| Reactant | Benzaldehyde | HCID 240 | — |
| Reactant | Propionic Acid | HCID 1032 | — |
| Reactant | Hydantoin | HCID 10006 | — |
| Product | 5-Benzylidenehydantoin | HCID 97857 | 94.6% |
Reaction Steps
To a mixture of 100 grams (1.0 mole) of hydantoin, 106 grams (1.0 mole) of benzaldehyde, and 370 grams (5.0 moles) of propionic acid, there were added 17 grams (1.0 mole) of ammonia. The mixture was subsequently held for 3 hours at reflux temperature. After the cooling off, there were obtained 178 grams of 5-benzylidene hydantoin, corresponding to 95% of theory based on hydantoin.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04345072 |
| Source dataset | uspto-grants-1982_08 |
| ORD ID | ord-b6bb45a4b7e84b40ba94557164a9d2d0 |
| Source note | uspto-grants-1982_08 |