HuagongsheHuagongshe Chemistry Print Report · For research reference only
Nitromethane → Methyl 4-(2-nitroethenyl)benzoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Nitromethane | HCID 6375 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | Methyl 4-Formylbenzoate | HCID 15294 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | Methyl 4-(2-nitroethenyl)benzoate | HCID 896295 | — |
Reaction Steps
Sodium hydroxide (1 N, 2.3 mL) was added dropwise to 4-formyl-benzoic acid methyl ester (0.33 g) and nitromethane (0.11 ml) in 5 mL methanol at 0° C. The solution was acidified after 0.5 h and a precipitate was formed. The precipitate was isolated by filtration to give 228 mg of 4-(2-nitro-vinyl)-benzoic acid methyl ester.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07084154B2 |
| Source dataset | uspto-grants-2006_08 |
| ORD ID | ord-bbf5b318502845ec93a68e348bf67846 |
| Source note | uspto-grants-2006_08 |