Acetic Acid → 3,5-Di-tert.butyl-4-hydroxybenzyl-malonic acid-bis(2,2,6,6-tetramethyl-4-piperidinyl)ester

HRID 809699

Reaction equation

HRID 809699 reaction equation
[C:1]([CH2:2][C:3](=[O:4])[O:5][CH:6]1[CH2:7][C:8]([CH3:14])([CH3:15])[NH:9][C:10]([CH3:12])([CH3:13])[CH2:11]1)(=[O:16])[O:17][CH:18]1[CH2:19][C:20]([CH3:26])([CH3:27])[NH:21][C:22]([CH3:24])([CH3:25])[CH2:23]1.[C:28]([CH3:29])([CH3:30])([CH3:31])[c:32]1[cH:33][c:34]([CH2:35][N:36]([CH3:37])[CH3:38])[cH:39][c:40]([C:43]([CH3:44])([CH3:45])[CH3:46])[c:41]1[OH:42].[CH3:49][C:50](=[O:51])[OH:52].[CH3:53][c:54]1[cH:55][cH:56][cH:57][cH:58][cH:59]1.[Li:47].[NH2-:48]>>[C:1]([CH:2]([C:3](=[O:4])[O:5][CH:6]1[CH2:7][C:8]([CH3:14])([CH3:15])[NH:9][C:10]([CH3:12])([CH3:13])[CH2:11]1)[CH2:35][c:34]1[cH:33][c:32]([C:28]([CH3:29])([CH3:30])[CH3:31])[c:41]([OH:42])[c:40]([C:43]([CH3:44])([CH3:45])[CH3:46])[cH:39]1)(=[O:16])[O:17][CH:18]1[CH2:19][C:20]([CH3:26])([CH3:27])[NH:21][C:22]([CH3:24])([CH3:25])[CH2:23]1

Participants

7

Reactant 6

HCID 176Acetic AcidHCID 1140TolueneHCID 66609Phenol, 4-[(dimethylamino)methyl]-2,6-bis(1,1-dimethylethyl)-HCID 1244568Bis(2,2,6,6-tetramethylpiperidin-4-yl) propanedioateHCID 2826723AzanideHCID 3028194Lithium

Product 1

HCID 140938763,5-Di-tert.butyl-4-hydroxybenzyl-malonic acid-bis(2,2,6,6-tetramethyl-4-piperidinyl)ester

Sources & evidence

ORD record
ord-f514c7a334e2494c98c0f1161444d6be
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Linked notes

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