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Bromide ion → 1,1-Dimethyl-4-methylidenecyclohexane

HRID 809780
Notes
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Reaction equation

HRID 809780 reaction equation
[Br-:16].[CH3:17][P+:18]([c:19]1[cH:20][cH:21][cH:22][cH:23][cH:24]1)([c:25]1[cH:26][cH:27][cH:28][cH:29][cH:30]1)[c:31]1[cH:32][cH:33][cH:34][cH:35][cH:36]1.[CH3:1][S:2]([CH3:3])=[O:4].[CH3:7][C:8]1([CH3:15])[CH2:9][CH2:10][C:11](=[O:14])[CH2:12][CH2:13]1.[H-:5].[Na+:6].[OH2:37]>>[CH2:1]=[C:11]1[CH2:10][CH2:9][C:8]([CH3:7])([CH3:15])[CH2:13][CH2:12]1
ParticipantsSources & evidenceReaction notes

Participants

8

Reactant 7

HCID 259Bromide ionHCID 679Dimethyl SulfoxideHCID 923Sodium IonHCID 962WaterHCID 74506TriphenylmethylphosphoniumHCID 138166Cyclohexanone, 4,4-dimethyl-HCID 166653Hydride

Product 1

HCID 5729641,1-Dimethyl-4-methylidenecyclohexane

Sources & evidence

ORD record
ord-865631cf11da48378bd43327e6cc1002
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D
DOI
10.1039/C8SC04228D

Reaction notes

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On this pageParticipantsSources & evidenceReaction notes