Acetone → HCID 86664979, compound

HRID 83952

Reaction equation

O.CC(C)=O.[C:6]([O:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])(=[O:9])[CH:7]=[CH2:8].C=C1CCOC1=O.C([O-])(=O)CCCCCCCCCCCCCCCCC.[Na+].S(OOS([O-])(=O)=O)([O-])(=O)=O.[Na+].[Na+]>>[CH2:14]=[C:13]1[CH2:12][CH2:11][O:10][C:6]1=[O:9].[C:6]([O:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])(=[O:9])[CH:7]=[CH2:8]

Participants

Reactant 6

HCID 180Acetone

HCID 962Water

HCID 62552Stearyl acrylate

HCID 62655Sodium Persulfate

HCID 68352alpha-Methylene butyrolactone

HCID 2724691Sodium Stearate

Product 1

HCID 86664979HCID 86664979, compound

Conditions

Temperature: 60 °C

Procedure

To a high-pressure reactor with a magnetic stirrer is charged 31.50 g (1.75 mol) water, 13.50 g (0.232 mol) acetone, 25.0 g (7.70×10−2 mol) octadecyl acrylate, 25.0 g (0.255 mol) α-methylene-γ-butyrolactone, 1.25 g (4.08×10−3 mol) sodium stearate, and 0.13 g (5.46×10−4 mol) sodium persulfate. Two freeze-pump-thaw cycles using liquid nitrogen sufficiently degass the reaction medium prior to sealing the reactor and heating to 60° C. The reaction is stirred for 16 hours at 60° C. before cooling to room temperature and drying under vacuum at elevated temperature for isolation.

Workup

customsufficiently degass the reaction medium
temperaturebefore cooling to room temperature
customdrying under vacuum at elevated temperature for isolation

Sources & evidence

ORD record: ord-0ab276d882e44ad1b14ab99621658f7b
Source dataset: uspto-grants-2014_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08846817B2

Linked notes

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