Chlorotrimethylsilane → 1-Chloro-3,7-dimethyl-octa-2,6-diene
Reaction equation
[CH2:1]=[CH:2][C:3]([CH2:6][CH2:7][CH:8]=[C:9]([CH3:11])[CH3:10])([CH3:5])O.C[Si](C)(C)[Cl:14]>[Bi+]=O>[Cl:14][CH2:1][CH:2]=[C:3]([CH3:5])[CH2:6][CH2:7][CH:8]=[C:9]([CH3:11])[CH3:10]Participants
4
Reactant 2
Product 1
Reagents, catalysts & solvents 1
Conditions
- Temperature
- 60 °C
Procedure
To a mixture of 170 g linalool and 20 mg bismuth(III)-oxide heated to 60° C., 130.5 g trimethylchlorosilane were dropped in. Then the mixture was cooled to room temperature and the organic layer was separated. The resulting oil was purified by distillation to yield 158.35 g of a colorless oil.
Workup
- temperatureThen the mixture was cooled to room temperature
- customthe organic layer was separated
- distillationThe resulting oil was purified by distillation
Sources & evidence
- ORD record
- ord-93b7fdeaec43433281661a380319a923
- Source dataset
- uspto-grants-2002_04
- Patent number
- US06369248B1
Reaction notes
Loading…