7-Methoxy-4-cyano chrom-3-ene → HCID 15023228, compound
Reaction equation
[CH3:1][O:2][C:3]1[CH:12]=[C:11]2[C:6]([C:7]([C:13]#[N:14])=[CH:8][CH2:9][O:10]2)=[CH:5][CH:4]=1>CO.N.[Ni]>[NH2:14][CH2:13][CH:7]1[C:6]2[C:11](=[CH:12][C:3]([O:2][CH3:1])=[CH:4][CH:5]=2)[O:10][CH2:9][CH2:8]1Participants
5
Reagents, catalysts & solvents 3
Procedure
The product from Example 1 was hydrogenated with RaNi in MeOH and NH3 at 4 atm. pressure and gave the desired product, (M+H)+ 194.
Sources & evidence
- ORD record
- ord-1e03c59d573841eebab64a11eed19576
- Source dataset
- uspto-grants-1992_08
- Patent number
- US05140039
Reaction notes
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