tert-Butanol → HCID 11770349, compound

HRID 847478

Reaction equation

HRID 847478 reaction equation
[CH:1]1([Si:6](OC)([O:9][CH3:10])[O:7][CH3:8])[CH2:5][CH2:4][CH2:3][CH2:2]1.[C:13]([OH:17])([CH3:16])([CH3:15])[CH3:14].CC(C)([O-])C.[K+].[Cl-].[NH4+]>>[C:13]([O:17][Si:6]([CH:1]1[CH2:5][CH2:4][CH2:3][CH2:2]1)([O:9][CH3:10])[O:7][CH3:8])([CH3:16])([CH3:15])[CH3:14]

Participants

5

Reactant 4

HCID 6386tert-ButanolHCID 25517Ammonium ChlorideHCID 9855701CyclopentyltrimethoxysilaneHCID 23665647Potassium tert-butoxide

Product 1

HCID 11770349HCID 11770349, compoundYield 21%

Conditions

Temperature
80 °C

Procedure

In a 100 ml three-neck flask provided with a magnetic stirrer and a reflux condenser were charged 25.0 g (0.131 mole) of cyclopentyl trimethoxysilane, 9.74 g (0.131 mole) of tert.-butyl alcohol and 20 mg (0.18 m mole) of potassium tert.-butoxide, which were then reacted with each other by heating under stirring in an oil both of 80° C. for 10 hours. After cooled, ammonium chloride was added to neutralize the alkali. Then, tert.-butoxy cyclopentyl dimethoxysilane of 6.25 g (0.0269 mole) was obtained by vacuum distillation. Its structure was confirmed as in Example 1. The yield was 21%.

Workup

  1. customIn a 100 ml three-neck flask provided with a magnetic stirrer and a reflux condenser
  2. customwere then reacted with each other
  3. temperatureby heating
  4. temperatureAfter cooled

Sources & evidence

ORD record
ord-79a65caf01b946a0b3ea613c70124241
Source dataset
uspto-grants-1992_08
Patent number
US05142082

Linked notes

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