HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Dodecene → n-Dodecyldichlorosilane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Dodecene | HCID 8183 | — |
| Reactant | Dichlorosilane | HCID 61330 | — |
| Catalyst | Nickel Dichloride | HCID 24385 | — |
| Product | n-Dodecyldichlorosilane | HCID 123720552 | — |
Reaction Steps
Dichlorosilane in an amount of 75.8 g (0.75 mol), 228.5 g of 1-dodecene (1.36 mol) and 0.05 mol % of a catalyst NiCl2 --(PPh3)2 (relative to dichlorosilane) were charged in a 500 ml pressure-proof stainless steel reactor and sealed. A reaction was carried out at 100° C. for 30 hours and the reacted liquid was distilled to obtain n-dodecyldichlorosilane (n--C12H25SiHCl2).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04297499 |
| Source dataset | uspto-grants-1981_10 |
| ORD ID | ord-619ad426c84a4feb889b047bc5e498c7 |
| Source note | uspto-grants-1981_10 |