Oxonium, trimethyl-, tetrafluoroborate(1-) (1:1) → HCID 54560967, compound
Reaction equation
[C:1]1([CH:7]=[CH:8][CH2:9][CH:10]2[NH:16][C:15](=[O:17])[CH2:14][CH2:13][CH2:12][CH2:11]2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.F[B-](F)(F)F.[CH3:23][O+](C)C>C(Cl)Cl>[CH3:23][O:17][C:15]1[CH2:14][CH2:13][CH2:12][CH2:11][CH:10]([CH2:9][CH:8]=[CH:7][C:1]2[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=2)[N:16]=1Participants
4
Reactant 2
Product 1
Reagents, catalysts & solvents 1
Procedure
The title material of Example 32 (0.50 g, 2.2 mmol) in CH2Cl2 (15 mL) and in the presence of 3A molecular sieves (1.0 g) was reacted with trimethyloxonium tetrafluoroborate (0.39 g, 2.6 mmol) by the method of Example 3 to produce 0.53 g (99%) of the title material.
Sources & evidence
- ORD record
- ord-8f5e4843415d481098c2b8e8c9926d1f
- Source dataset
- uspto-grants-2000_01
- Patent number
- US06011028
Reaction notes
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