Ioxynic acid → Methyl 4-hydroxy-3,5-diiodobenzoate

HRID 852622

Reaction equation

[CH3:1]OC(=O)C1C=C([N+]([O-])=O)C(OC)=C([N+]([O-])=O)C=1.[OH:19][C:20]1[C:28]([I:29])=[CH:27][C:23]([C:24]([OH:26])=[O:25])=[CH:22][C:21]=1[I:30]>>[OH:19][C:20]1[C:21]([I:30])=[CH:22][C:23]([C:24]([O:26][CH3:1])=[O:25])=[CH:27][C:28]=1[I:29]

Participants

Reactant 2

HCID 12065Ioxynic acid

HCID 14091421Methyl 4-methoxy-3,5-dinitrobenzoate

Product 1

HCID 12207035Methyl 4-hydroxy-3,5-diiodobenzoate

Procedure

Methyl 4-hydroxy-3,5-diiodobenzoate (D254) was prepared in an analogous manner to Description 25 (D25) from commercially available 4-hydroxy-3,5-diiodobenzoic acid.

Sources & evidence

ORD record: ord-45cb3009486240a59bb49fe6b5e5a426
Source dataset: uspto-grants-2007_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07253198B2

Linked notes

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