Acrolein → N-(4-Chlorobenzylidene)-4-methylthioaniline

HRID 856817

Reaction equation

HRID 856817 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([CH:8]([NH:11][C:12]2[CH:17]=[CH:16][C:15]([S:18][CH3:19])=[CH:14][CH:13]=2)C#N)=[CH:4][CH:3]=1.C(C=C)=O>>[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([CH:8]=[N:11][C:12]2[CH:17]=[CH:16][C:15]([S:18][CH3:19])=[CH:14][CH:13]=2)=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 7847AcroleinHCID 21862778alpha-(4-Chlorophenyl)-alpha-(4-methylthioanilino)acetonitrile

Product 1

HCID 21862850N-(4-Chlorobenzylidene)-4-methylthioaniline

Procedure

Following a procedure similar to that described in Example 21(iii), but using α-(4-chlorophenyl)-α-(4-methylthioanilino)acetonitrile [prepared as described in step (ii) above] and acrolein as starting materials, the title compound was obtained as an orange-colored powder (yield 32%), melting at 203-205° C.

Sources & evidence

ORD record
ord-e8566af10da04d4cb67722f52d006b8e
Source dataset
uspto-grants-2006_12
Patent number
USRE039420E1

Linked notes

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