2-Butyl-2-ethyl-1,3-propanediol → 5-Butyl-5-ethyl-2-(4-nitrobenzyl)-1,3,2-dioxaphosphorinan-2-oxide

HRID 861876

Reaction equation

HRID 861876 reaction equation
[N+:1]([C:4]1[CH:14]=[CH:13][C:7]([CH2:8][P:9](=[O:12])([OH:11])[OH:10])=[CH:6][CH:5]=1)([O-:3])=[O:2].[CH2:15]([C:19]([CH2:24][CH3:25])([CH2:22]O)[CH2:20]O)[CH2:16][CH2:17][CH3:18]>>[CH2:15]([C:19]1([CH2:24][CH3:25])[CH2:22][O:11][P:9](=[O:10])([CH2:8][C:7]2[CH:13]=[CH:14][C:4]([N+:1]([O-:3])=[O:2])=[CH:5][CH:6]=2)[O:12][CH2:20]1)[CH2:16][CH2:17][CH3:18]

Participants

3

Reactant 2

HCID 610382-Butyl-2-ethyl-1,3-propanediolHCID 5180708(4-Nitro-benzyl)-phosphonic acid

Product 1

HCID 189280705-Butyl-5-ethyl-2-(4-nitrobenzyl)-1,3,2-dioxaphosphorinan-2-oxide

Procedure

4-Nitrobenzylphosphonic acid and 2-butyl-2-ethyl-1,3-propanediol were treated in the same manner as in Reference Example 20 to yield 5-butyl-5-ethyl-2-(4-nitrobenzyl)-1,3,2-dioxaphosphorinan-2-oxide, which was then recrystallized from ethanol-hexane to yield colorless prisms having a melting point of 111°-112° C.

Sources & evidence

ORD record
ord-c4d737db100d4be8abd78afdda316df1
Source dataset
uspto-grants-1998_02
Patent number
US05716944

Linked notes

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