Dibenzyl sulfide → C6H5CH2SP(S)Cl2

HRID 866628

Reaction equation

[CH2:1]([S:9][P:10]([Cl:13])([Cl:12])=[S:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7]C.S(CC1C=CC=CC=1)CC1C=CC=CC=1.S(CCCCCCCC)CCCCCCCC>>[C:2]1([CH2:1][S:9][P:10]([Cl:12])([Cl:13])=[S:11])[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

Participants

Reactant 3

HCID 10867Dibenzyl sulfide

HCID 75901Dioctyl sulfide

HCID 15833785n-C8H17SP(S)Cl2

Product 1

HCID 14939050C6H5CH2SP(S)Cl2Yield 53%

Procedure

Following the procedure and employing the reaction temperature and reactants of Example 7 with the exception that 53.5 grams (0.25 mole) of (C6H5CH2)2S were employed as a reactant instead of (n-C8H17)2S, 68 grams (53% yield)of C6H5CH2SP(S)Cl2 was obtained. The product had the following properties:

Sources & evidence

ORD record: ord-05154d3b49bd4f219f5bcec5a8ff4c21
Source dataset: uspto-grants-1978_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04100230

Linked notes

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