Toluene → Tungsten oxide toluene

HRID 870104Notes

Reaction equation

HRID 870104 reaction equation
[W:1]=[O:2].C(OC=C)(=O)C.C=C.[C:11]1([CH3:17])[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1>>[C:11]1([CH3:17])[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1.[W:1]=[O:2]

Participants

4

Reactant 3

HCID 1140Toluene2×HCID 139486OxotungstenHCID 175988Ethene;ethenyl acetate2×

Product 1

HCID 86725072Tungsten oxide toluene

Procedure

100 g of tungsten oxide powder (Cs0.33WO2.94Cl0.02Br0.04) was ground and dispersed in 500 g of toluene, and added with 10% ethylene vinyl acetate (EVA) relative to the weight of the aforesaid powder, to enable the EVA to dissolve in toluene. Then, an anion and cation co-doped tungsten oxide toluene solution was obtained.

Sources & evidence

ORD record
ord-a1f9b9324c2d4f12a761b44adeff879c
Source dataset
uspto-grants-2015_03
Patent number
US08969458B2

Reaction notes

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