Benzothiazol-5-amine → 2-Isopropylbenzo[d]thiazol-5-amine

Reaction equation

[CH:1]([C:4]1[S:5][C:6]2[CH:12]=[CH:11][C:10]([N+:13]([O-])=O)=[CH:9][C:7]=2[N:8]=1)([CH3:3])[CH3:2].S1C2C=CC(N)=CC=2N=C1>>[CH:1]([C:4]1[S:5][C:6]2[CH:12]=[CH:11][C:10]([NH2:13])=[CH:9][C:7]=2[N:8]=1)([CH3:3])[CH3:2]

Participants

Reactant 2

HCID 70749Benzothiazol-5-amine

HCID 692626292-Isopropyl-5-nitrobenzo[d]thiazole

Product 1

HCID 450774932-Isopropylbenzo[d]thiazol-5-amine

Procedure

2-Isopropylbenzo[d]thiazol-5-amine was prepared from 2-isopropyl-5-nitrobenzo[d]thiazole similar to that described in the preparation benzo[d]thiazol-5-amine.

Sources & evidence

ORD record: ord-4846f5b862c34ae08bdeac920a93a159
Source dataset: uspto-grants-2012_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08247556B2

Reaction notes

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