Isobutylene → N-phenylmaleimide isobutene

HRID 891180Notes

Reaction equation

HRID 891180 reaction equation
C([O-])(=O)CCCC[CH2:6][C:7](C)([CH3:9])[CH3:8].[C:13]1([N:19]2[C:23](=[O:24])[CH:22]=[CH:21][C:20]2=[O:25])[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1.C=C(C)C>C1(C)C=CC=CC=1>[C:13]1([N:19]2[C:23](=[O:24])[CH:22]=[CH:21][C:20]2=[O:25])[CH:14]=[CH:15][CH:16]=[CH:17][CH:18]=1.[CH2:6]=[C:7]([CH3:9])[CH3:8]

Participants

5

Reactant 3

HCID 8255IsobutyleneHCID 13662N-PhenylmaleimideHCID 21225528Neodecanoate

Product 1

HCID 69501867N-phenylmaleimide isobutene

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

In a one-liter autoclave were charged 400 ml of toluene as a polymerization solvent, 0.001 moles of perbutyl neodecanoate as a polymerization initiator, 0.42 moles of N-phenylmaleimide, and 4.05 moles of isobutene, and the mixture was subjected to polymerization reaction under a polymerization condition at a polymerization temperature of 60° C. for a polymerization time of 5 hours, to obtain N-phenylmaleimide-isobutene alternating copolymer. The thus obtained N-phenylmaleimide-isobutene alternating copolymer had a weight average molecular weight (Mw) (as reduced into standard polystyrene) of 162,000 and an Mw/Mn of 2.6.

Workup

  1. customthe mixture was subjected to polymerization reaction under a polymerization condition at a polymerization temperature of 60° C. for a polymerization time of 5 hours

Sources & evidence

ORD record
ord-7996e10921c24b5780e9d828df5d9dd9
Source dataset
uspto-grants-2006_02
Patent number
US07001967B2

Reaction notes

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