Benzene → 2′-Methyl-4-nitro[1,1′-biphenyl]-2-amine

HRID 89515

Reaction equation

HRID 89515 reaction equation
[Br:1][c:2]1[c:3]([NH2:4])[cH:5][c:6]([N+:9](=[O:10])[O-:11])[cH:7][cH:8]1.[Na+:12].[Na+:13].[O-:14][C:15](=[O:16])[O-:17].[c:18]1([CH3:27])[c:19]([B:24]([OH:25])[OH:26])[cH:20][cH:21][cH:22][cH:23]1.[cH:28]1[cH:29][cH:30][cH:31][cH:32][cH:33]1>>[c:2]1(-[c:19]2[c:18]([CH3:27])[cH:23][cH:22][cH:21][cH:20]2)[c:3]([NH2:4])[cH:5][c:6]([N+:9](=[O:10])[O-:11])[cH:7][cH:8]1

Participants

6

Reactant 5

HCID 241BenzeneHCID 923Sodium ion2×HCID 19660Carbonate IonHCID 826072-Bromo-5-nitroanilineHCID 27332672-Methylphenyl boronic acid

Product 1

HCID 185464992′-Methyl-4-nitro[1,1′-biphenyl]-2-amine

Sources & evidence

ORD record
ord-b43b2322aece4eb0b8d384bb5f49e707
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Linked notes

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