Ethyl 2-(4-bromo-2-chlorophenoxy)acetate → Ethyl (3,2'-dichloro-biphenyl-4-yloxy)-acetate

Reaction equation

Br[C:2]1[CH:14]=[CH:13][C:5]([O:6][CH2:7][C:8]([O:10][CH2:11][CH3:12])=[O:9])=[C:4]([Cl:15])[CH:3]=1.[Cl:16][C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=1OB(O)O>>[Cl:15][C:4]1[CH:3]=[C:2]([C:18]2[CH:19]=[CH:20][CH:21]=[CH:22][C:17]=2[Cl:16])[CH:14]=[CH:13][C:5]=1[O:6][CH2:7][C:8]([O:10][CH2:11][CH3:12])=[O:9]

Participants

Reactant 2

HCID 4508433Ethyl 2-(4-bromo-2-chlorophenoxy)acetate

HCID 219175802-Chlorophenylboric acid

Product 1

HCID 85969214Ethyl (3,2'-dichloro-biphenyl-4-yloxy)-acetate

Procedure

Prepared analogously to Example 130a from ethyl (4-bromo-2-chloro-phenoxy)-acetate (Z26) and 2-chlorophenylboric acid.

Sources & evidence

ORD record: ord-dfc5c4d5bde044c7858148c3b3c810eb
Source dataset: uspto-grants-2008_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07351719B2

Reaction notes

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