1,4-Butanediol → 4-allyloxy-1-butanol
Reaction equation
C(O)CCCO.C(OCC=C)(=O)C.[CH2:14]([O:17][CH2:18][CH2:19][CH2:20][CH2:21][O:22]CC=C)[CH:15]=[CH2:16]>>[CH2:14]([O:17][CH2:18][CH2:19][CH2:20][CH2:21][OH:22])[CH:15]=[CH2:16]Participants
4
Procedure
A reaction was performed by the procedure of Example 1, except for using 1,4-butanediol instead of 1-octanol and using allyl acetate in an amount of 10 mmol. The reaction mixture was analyzed by gas chromatography to find that 3-(4-allyloxy-butoxy)-propene and 4-allyloxy-1-butanol were formed in yields of 78% and 6%, respectively.
Sources & evidence
- ORD record
- ord-6e9bbf06a71f465b94c7af0a7f945173
- Source dataset
- uspto-grants-2007_12
- Patent number
- US07304184B2
Reaction notes
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