6-Deoxyglucose → (2R,3R,4S,5S)-2,3,4,5-tetrahydroxyhexanal

HRID 978185

Reaction equation

[O:1]=[CH:2][C@@H:3]([C@H:5]([C@@H:7]([C@@H:9]([CH3:11])[OH:10])[OH:8])[OH:6])[OH:4].OCC([C@H]([C@@H]([C@@H](C)O)O)O)=O>>[O:1]=[CH:2][C@@H:3]([C@@H:5]([C@H:7]([C@H:9]([CH3:11])[OH:10])[OH:8])[OH:6])[OH:4]

Participants

Reactant 2

HCID 935796-Deoxyglucose

HCID 117449636-Deoxy-D-fructose

Product 1

HCID 19233(2R,3R,4S,5S)-2,3,4,5-tetrahydroxyhexanal

Procedure

6-Deoxy-D-glucose→6-deoxy-D-arabino-hexulose (otherwise 6-deoxy-D-fructose)

Sources & evidence

ORD record: ord-21fa97d1acb0498bb3ca09f0de7aecce
Source dataset: uspto-grants-1987_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04663449

Linked notes

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