Methyl iodide → HCID 13749901, compound

Reaction equation

CO[C:3]1[CH:4]=[C:5]2[C:14](=[CH:15][CH:16]=1)[NH:13][C:12]1[N:11]=[CH:10][CH:9]=[N:8][C:7]=1[S:6]2.[CH3:17][O:18][C:19](Cl)=[O:20].CI>>[C:19]([N:13]1[C:12]2[N:11]=[CH:10][CH:9]=[N:8][C:7]=2[S:6][C:5]2[C:14]1=[CH:15][CH:16]=[CH:3][CH:4]=2)([O:18][CH3:17])=[O:20]

Participants

Reactant 3

HCID 6328Methyl iodide

HCID 6586Methyl chloroformate

HCID 137498967-Methoxy 1,4-diazaphenothiazine

Product 1

HCID 13749901HCID 13749901, compoundYield 23%

Procedure

By following the conditions of Example 4, but substituting 1,4-diazaphenothiazine for 7-methoxy 1,4-diazaphenothiazine and methylchloroformate for methyl iodide, the title compound, m.p. 137°-138° was obtained in a 23% yield.

Sources & evidence

ORD record: ord-f206a4c0d49045a8958a9aa1a2a2261e
Source dataset: uspto-grants-1987_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04634766

Reaction notes

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