2-Ethylhexanoylbenzene → 2-Ethylhexylbenzene

HRID 983746

Reaction equation

HRID 983746 reaction equation
[CH2:1]([CH:3]([CH2:12][CH2:13][CH2:14][CH3:15])[C:4]([C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)=O)[CH3:2].[H][H]>C(O)(=O)C.[Pd]>[CH2:1]([CH:3]([CH2:12][CH2:13][CH2:14][CH3:15])[CH2:4][C:6]1[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=1)[CH3:2]

Participants

5

Reactant 2

HCID 222694662-EthylhexanoylbenzeneHCID 178418361HCID 178418361, compound

Product 1

HCID 221170152-Ethylhexylbenzene

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 176Acetic AcidSolvent

Procedure

A solution of 313.9 grams of 2-ethylhexanoylbenzene in 500 mL of acetic acid with 11.4 grams of 10% palladium on carbon (as a catalyst) was stirred at 110° C. in an atmosphere of hydrogen at 414 kPa for 34 hours. The mixture was filtered through Celite™ diatomaceous earth filter agent to remove the catalyst. The filtrate was concentrated in vacuo to give 2-ethylhexylbenzene.

Workup

  1. filtrationThe mixture was filtered through Celite™ diatomaceous earth
  2. filtrationfilter agent
  3. customto remove the catalyst
  4. concentrationThe filtrate was concentrated in vacuo

Sources & evidence

ORD record
ord-f89aaa69874e4a94bce47ae520faaaf6
Source dataset
uspto-grants-2005_03
Patent number
US06864396B2

Linked notes

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