2,5-Bis(chloromethyl)-1-methoxy-4-(3',7'-dimethyloctyloxy)benzene → HCID 68619000, compound
Reaction equation
ClCC1C=C(OC)C(CCl)=CC=1OCCC(C)CCCC(C)C.[Cl:24][CH2:25][C:26]1[CH:31]=[C:30](OC)[C:29](CCl)=[CH:28][C:27]=1[C:36]1[CH:41]=[CH:40][CH:39]=[C:38]([O:42][CH2:43][CH2:44][CH:45]([CH3:52])[CH2:46][CH2:47][CH2:48][CH:49]([CH3:51])[CH3:50])[CH:37]=1>O1CCOCC1>[Cl:24][CH2:25][C:26]1[CH:31]=[CH:30][CH:29]=[CH:28][C:27]=1[C:36]1[CH:41]=[CH:40][CH:39]=[C:38]([O:42][CH2:43][CH2:44][CH:45]([CH3:52])[CH2:46][CH2:47][CH2:48][CH:49]([CH3:51])[CH3:50])[CH:37]=1Participants
4
Reactant 2
Product 1
Reagents, catalysts & solvents 1
Procedure
7.47 g (28.5 mmol) of 1,4-bis(chloromethyl)-2-(3,7-dimethyloctyloxy)-5-methoxybenzene (Ex. Z1), 6.22 g (17.1 mmol) of 2,5-bis(chloromethyl)4-methoxy-3′-(3,7-dimethyloctyloxy)biphenyl (Ex. E2) and 4.64 g (11.4 mmol) of 2,5-bis(chloromethyl-3′-(3,7-dimethyloctyloxy)biphenyl (Ex. Z3) in 3450 ml of dry 1,4-dioxane were polymerized at 98-100° C. analogously to