1,3-Benzodioxol-5-amine, N-methyl- → HCID 13098801, compound

Reaction equation

[CH3:1][NH:2][C:3]1[CH:8]=[CH:7][C:6]2[O:9][CH2:10][O:11][C:5]=2[CH:4]=1.[O:12]([C:14]#[N:15])[Na]>>[CH3:1][N:2]([C:3]1[CH:8]=[CH:7][C:6]2[O:9][CH2:10][O:11][C:5]=2[CH:4]=1)[C:14]([NH2:15])=[O:12]

Participants

Reactant 2

HCID 106069191,3-Benzodioxol-5-amine, N-methyl-

HCID 178418852HCID 178418852, compound

Product 1

HCID 13098801HCID 13098801, compoundYield 56%

Procedure

The title compound was prepared from N-methyl-3,4-(methylenedioxy)aniline and NaOCN by the procedure described in example 1in 56% yield. 1H NMR (CDCl3): 6.75-6.64 (m, 3H), 6.02 (s, 2H), 4.42 (br s, 2H), 3.21(s, 3H).

Sources & evidence

ORD record: ord-5ee5e66cef2f4b389f1d0d7ceb0dfc64
Source dataset: uspto-grants-2002_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06465472B1

Reaction notes

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