Pyridine → 1,2,3,4-Tetrahydro-6-methoxy-1-methyl-2-oxo-4-quinolineacetaldehyde

HRID 99545

Reaction equation

HRID 99545 reaction equation
[Cl:28][CH2:29][Cl:30].[O:7]=[Cr:8](=[O:9])=[O:10].[OH:11][CH2:12][CH2:13][CH:14]1[CH2:15][C:16](=[O:27])[N:17]([CH3:26])[c:18]2[cH:19][cH:20][c:21]([O:24][CH3:25])[cH:22][c:23]21.[cH:1]1[cH:2][cH:3][n:4][cH:5][cH:6]1>>[O:11]=[CH:12][CH2:13][CH:14]1[CH2:15][C:16](=[O:27])[N:17]([CH3:26])[c:18]2[cH:19][cH:20][c:21]([O:24][CH3:25])[cH:22][c:23]21

Participants

5

Reactant 4

HCID 1049PyridineHCID 6344DichloromethaneHCID 14915Chromium TrioxideHCID 156788713,4-dihydro-4-(2-hydroxyethyl)-6-methoxy-1-methyl-2(1H)-quinolinone

Product 1

HCID 156788721,2,3,4-Tetrahydro-6-methoxy-1-methyl-2-oxo-4-quinolineacetaldehyde

Sources & evidence

ORD record
ord-55b4e18660c442d9b41c5f1d3562db68
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Linked notes

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