Cobalt hydroxide

HCID 10129900

基本情報

CAS
12672-51-4
標準SMILES
[Co+2].[OH-].[OH-]
InChIKey
ASKVAEGIVYSGNY-UHFFFAOYSA-L
分子式
CoH2O2
平均分子量
92.948 g/mol
単同位体質量
92.9386743

概要

Cobalt(II) hydroxide Co(OH)2 is a hydroxide of cobalt. It occurs in two forms, either as a rose-red powder, which is the more stable of the two forms, or as bluish-green powder. It is used as a drying agent for paints, varnishes, and inks, in the preparation of other cobalt compounds, as a catalyst, or in the manufacture of battery electrodes. Cobalt is a metallic element with the atomic number 27. It is found naturally in rocks, soil, water, plants, and animals. In small amounts cobalt is an essential element for life, as it is part of vitamin B12. However, excess exposure is known to exhibit toxic effects. (L29, L30, L490)

名称と識別子

優先名称
Cobalt hydroxide
IUPAC
cobalt(2+) dihydroxide
英語名
Cobalt hydroxide
分子式
Co(HO)2
分子量
92.948

名称と別名

COBALT HYDROXIDE21041-93-0Cobaltous hydroxide12672-51-4Cobalt(2+) hydroxideEINECS 235-763-051B9AYG60KCOBALTOUS HYDROXIDE [MI]RefChem:127211235-763-0244-166-4EC 244-166-4
名称をさらに表示
Cobalt hydroxide ISO 9001:2015 REACH
EINECS 244-166-4UNII-51B9AYG60KCobalt(II) hydroxidecobalt(2+);dihydroxidecobaltous;dihydroxideCoH2O2H2CoO2SCHEMBL73275

データベース識別子

CAS
12672-51-4、21041-93-0
PubChem CID
10129900
DTXSID
DTXSID70894155
UNII
51B9AYG60K
EC Number
235-763-0
Nikkaji
J96.009H

物性

構造計算による物性

極性表面積
2 Ų
水素結合供与体数
2
水素結合受容体数
2
回転可能結合数
0
重原子数
3

実験および物理化学的性質

Chemical Classes · 2 件

Metals -> Metals, Inorganic Compounds

Metals -> Metals, Inorganic Compounds

Physical Description · 2 件

CBI; Dry Powder; Wet Solid; Dry Powder; Wet Solid; Other Solid

Blue-green or rose-red solid (red form more stable); [Merck Index] Pink powder, practically insoluble in water; [MSDSonline]

物理化学的性質

融点
168 ° · 168 ° C (334.4 ° F)
比重(密度)
3.597 g/cm3 · 3.597 g/cm3
外見
powder
色
Red or bluish-green
水溶解度
3.2 mg/L · 3.20 mg/L
InChI
InChI=1S/Co.2H2O/h;2*1H2/q+2;;/p-2

安全と法規制

GHS分類

GHS Classification · 6 件

This chemical does not meet GHS hazard criteria for 100% (104 of 104) of all reports.

Not Classified

Aggregated GHS information provided per 104 reports by companies from 1 notifications to the ECHA C&L Inventory.

Danger

H302: Harmful if swallowed [Warning Acute toxicity, oral]

P203, P233, P260, P261, P264, P264+P265, P270, P271, P272, P280, P284, P301+P317, P302+P352, P304+P340, P305+P351+P338, P316, P318, P319, P320, P321, P330, P333+P317, P337+P317, P342+P316, P362+P364, P403, P403+P233, P405, and P501 (click each P-code to see the statement)

危険有害性情報

Regulatory Information · 4 件

Chemical: Cobalt(II) hydroxide

Cobalt hydroxide (Co(OH)2) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Cobalt hydroxide (Co(OH)2) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Cobalt hydroxide (mixed): Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Cobalt hydroxide: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Cobalt(II) hydroxide (Co(OH)2): Human health tier II assessment
Hazards Summary · 2 件

May be harmful; May cause skin sensitization; [MSDSonline] See Cobalt.

See Cobalt.

Hazard Classes and Categories · 2 件

Not Classified

Eye irritation - category 2A

安全と保護具

Exposure Control and Personal Protection · 2 件

Biological Exposure Indices (BEI) [ACGIH] - Cobalt in urine = 15 ug/L; sample at end of shift at end of workweek;

Biological Exposure Indices (BEI) [ACGIH] - Cobalt in urine = 15 ug/L; sample at end of shift at end of workweek;

Minimum Risk LevelChronic Inhalation: 0.0001 mg/m3 (L134) Intermediate Oral: 0.01 mg/kg/day (L134)
Threshold Limit Values (TLV) · 2 件

0.02 [mg/m3], as Co

0.02 [mg/m3], as Co

Protective Action Criteria (PAC) · 3 件

0.095 [mg/m3]

0.37 [mg/m3]

2.2 [mg/m3]

毒性情報

TreatmentTreatment of cobalt poisoning is symptomatic. (L29)
Health EffectsExposure to high amount of cobalt can cause heart, lung, kidney, and liver damage. Skin contact is known to result in contact dermatitis. Cobalt may also have mutagenic and carcinogenic effects. (L29, L30)
Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.
Exposure RoutesInhalation (L29) ; oral (L29) ; dermal (L29)
Toxicity Summary · 1 件

Cobalt is believed to exhibit its toxicity through a oxidant-based and free radical-based processes. It produces oxygen radicals and may be oxidized to ionic cobalt, causing increased lipid peroxidation, DNA damage, and inducing certain enzymes that lead to cell apoptosis. Cobalt has also been shown to block inorganic calcium channels, possibly impairing neurotransmission. Cobalt can also chelate lipoic acids, impairing oxidation of pyruvate or fatty acids. In addition, cobalt may inhibit DNA repair by interacting with zinc finger DNA repair proteins, and has also been shown to inhibit heme synthesis and glucose metabolism. Cobalt may activate specific helper T-lymphocyte cells and interact directly with immunologic proteins, such as antibodies (IgA and IgE) or Fc receptors, resulting in immunosensitization. (L29)

Signs and SymptomsCobalt inhalation can cause asthma-like breathing problems. Skin contact is known to result in contact dermatitis, which is characterized by irritation and rashes. Ingesting large amounts of cobalt may cause nausea and vomiting. (L2090)

化学と産業

薬理情報

Metabolism/Metabolites · 1 件

Cobalt is absorbed though the lungs, gastrointestinal tract, and skin. Since it is a component of the vitamin B12 (cyanocobalamin), it is distributed to most tissues of the body. It is transported in the blood, often bound to albumin, with the highest levels being found in the liver and kidney. Cobalt is excreted mainly in the urine and faeces. (L29)

用途と製造

Uses · 3 件

Used to make cobalt compounds, as a drier for paints, to aid drying of lithographic inks, and in storage battery electrode impregnating solutions; [Merck Index]

Battery Manufacturing [Category: Industry]

Cobalt(II) hydroxide is used as a drying agent for paints, varnishes, and inks, in the preparation of other cobalt compounds, as a catalyst, or in the manufacture of battery electrodes. (L490)

U.S. Production2023: 4,000,000 - <5,500,000 lb
Consumer UsesCatalyst
Industry UsesConductive agent
General Manufacturing Information · 2 件

Agriculture, Forestry, Fishing and Hunting

Cobalt hydroxide (Co(OH)2): ACTIVE

応用分野 · 1 件

使用Cobalt hydroxide is an important organic raw material in the fields of chemistry, materials and technical engineering and is used in the preparation of cement-based structural supercapacitors, as a colouring agent for glass and enamel, as a raw material for other cobalt compounds, and as a drying agent for varnishes and paints[1].

サプライヤー48 社

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湖北万得化工有限公司15377098680 15377098680 · [email protected]
Hebei Chuanghai Biotechnology Co., Ltd+86-17732866630 · [email protected]
山东泰诚生物科技有限公司18769832557 18769832557 · [email protected]
广州纳珑化工有限公司13192879270; 13192879270 · [email protected]

関連反応

6 件

化合物ノート

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