基本情報
- CAS
12672-51-4- 標準SMILES
[Co+2].[OH-].[OH-]- InChIKey
ASKVAEGIVYSGNY-UHFFFAOYSA-L- 分子式
- CoH2O2
- 平均分子量
- 92.948 g/mol
- 単同位体質量
- 92.9386743
概要
Cobalt(II) hydroxide Co(OH)2 is a hydroxide of cobalt. It occurs in two forms, either as a rose-red powder, which is the more stable of the two forms, or as bluish-green powder. It is used as a drying agent for paints, varnishes, and inks, in the preparation of other cobalt compounds, as a catalyst, or in the manufacture of battery electrodes. Cobalt is a metallic element with the atomic number 27. It is found naturally in rocks, soil, water, plants, and animals. In small amounts cobalt is an essential element for life, as it is part of vitamin B12. However, excess exposure is known to exhibit toxic effects. (L29, L30, L490)
名称と識別子
- 優先名称
- Cobalt hydroxide
- IUPAC
- cobalt(2+) dihydroxide
- 英語名
- Cobalt hydroxide
- 分子式
- Co(HO)2
- 分子量
- 92.948
名称と別名
名称をさらに表示
データベース識別子
- CAS
12672-51-4、21041-93-0- PubChem CID
- 10129900
- DTXSID
DTXSID70894155- UNII
- 51B9AYG60K
- EC Number
- 235-763-0
- Nikkaji
- J96.009H
物性
構造計算による物性
- 極性表面積
- 2 Ų
- 水素結合供与体数
- 2
- 水素結合受容体数
- 2
- 回転可能結合数
- 0
- 重原子数
- 3
- 形式電荷
- 0
- 複雑度
- 0
実験および物理化学的性質
Chemical Classes
Metals -> Metals, Inorganic Compounds
Metals -> Metals, Inorganic Compounds
Physical Description
CBI; Dry Powder; Wet Solid; Dry Powder; Wet Solid; Other Solid
Blue-green or rose-red solid (red form more stable); [Merck Index] Pink powder, practically insoluble in water; [MSDSonline]
物理化学的性質
- 融点
- 168 ° · 168 ° C (334.4 ° F)
- 比重(密度)
- 3.597 g/cm3 · 3.597 g/cm3
- 外見
- powder
- 色
- Red or bluish-green
- 水溶解度
- 3.2 mg/L · 3.20 mg/L
- InChI
- InChI=1S/Co.2H2O/h;2*1H2/q+2;;/p-2
- InChIKey
- ASKVAEGIVYSGNY-UHFFFAOYSA-L
- SMILES
- [Co+2].[O-][H].[O-][H]
安全と法規制
GHS分類
GHS Classification
This chemical does not meet GHS hazard criteria for 100% (104 of 104) of all reports.
Not Classified
Aggregated GHS information provided per 104 reports by companies from 1 notifications to the ECHA C&L Inventory.
Danger
H302: Harmful if swallowed [Warning Acute toxicity, oral]
P203, P233, P260, P261, P264, P264+P265, P270, P271, P272, P280, P284, P301+P317, P302+P352, P304+P340, P305+P351+P338, P316, P318, P319, P320, P321, P330, P333+P317, P337+P317, P342+P316, P362+P364, P403, P403+P233, P405, and P501 (click each P-code to see the statement)
危険有害性情報
Regulatory Information
Chemical: Cobalt(II) hydroxide
Cobalt hydroxide (Co(OH)2) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Cobalt hydroxide (Co(OH)2) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Cobalt hydroxide (mixed): Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
Cobalt hydroxide: Does not have an individual approval but may be used under an appropriate group standard
Hazards Summary
May be harmful; May cause skin sensitization; [MSDSonline] See Cobalt.
See Cobalt.
Hazard Classes and Categories
Not Classified
Eye irritation - category 2A
安全と保護具
Exposure Control and Personal Protection
Biological Exposure Indices (BEI) [ACGIH] - Cobalt in urine = 15 ug/L; sample at end of shift at end of workweek;
Biological Exposure Indices (BEI) [ACGIH] - Cobalt in urine = 15 ug/L; sample at end of shift at end of workweek;
Threshold Limit Values (TLV)
0.02 [mg/m3], as Co
0.02 [mg/m3], as Co
Protective Action Criteria (PAC)
0.095 [mg/m3]
0.37 [mg/m3]
2.2 [mg/m3]
毒性情報
Toxicity Summary
Cobalt is believed to exhibit its toxicity through a oxidant-based and free radical-based processes. It produces oxygen radicals and may be oxidized to ionic cobalt, causing increased lipid peroxidation, DNA damage, and inducing certain enzymes that lead to cell apoptosis. Cobalt has also been shown to block inorganic calcium channels, possibly impairing neurotransmission. Cobalt can also chelate lipoic acids, impairing oxidation of pyruvate or fatty acids. In addition, cobalt may inhibit DNA repair by interacting with zinc finger DNA repair proteins, and has also been shown to inhibit heme synthesis and glucose metabolism. Cobalt may activate specific helper T-lymphocyte cells and interact directly with immunologic proteins, such as antibodies (IgA and IgE) or Fc receptors, resulting in immunosensitization. (L29)
RAIS Toxicity Values
0.0077
CALEPA
化学と産業
薬理情報
Metabolism/Metabolites
Cobalt is absorbed though the lungs, gastrointestinal tract, and skin. Since it is a component of the vitamin B12 (cyanocobalamin), it is distributed to most tissues of the body. It is transported in the blood, often bound to albumin, with the highest levels being found in the liver and kidney. Cobalt is excreted mainly in the urine and faeces. (L29)
用途と製造
Uses
Used to make cobalt compounds, as a drier for paints, to aid drying of lithographic inks, and in storage battery electrode impregnating solutions; [Merck Index]
Battery Manufacturing [Category: Industry]
Cobalt(II) hydroxide is used as a drying agent for paints, varnishes, and inks, in the preparation of other cobalt compounds, as a catalyst, or in the manufacture of battery electrodes. (L490)
General Manufacturing Information
Agriculture, Forestry, Fishing and Hunting
Cobalt hydroxide (Co(OH)2): ACTIVE
応用分野
使用Cobalt hydroxide is an important organic raw material in the fields of chemistry, materials and technical engineering and is used in the preparation of cement-based structural supercapacitors, as a colouring agent for glass and enamel, as a raw material for other cobalt compounds, and as a drying agent for varnishes and paints[1].
サプライヤー48 社
関連反応
化合物ノート
読み込み中…