基本情報
- CAS
7790-79-6- 標準SMILES
[Cd+2].[F-].[F-]- InChIKey
LVEULQCPJDDSLD-UHFFFAOYSA-L- 分子式
- CdF2
- 平均分子量
- 150.41 g/mol
- 単同位体質量
- 151.900171
概要
Cadmium fluoride is a water-insoluble chemical compound of cadmium used in oxygen-sensitive applications, such as the production of metallic alloys. Cadmium is a transition metal and chemical element with the symbol Cd and atomic number 48. It is found naturally in the earth's crust, though rarely on it's own. (L6, L467)
名称と識別子
- 優先名称
- Cadmium fluoride [MI]
- IUPAC
- cadmium(2+) difluoride
- 現地名
- カドミウムジフルオリド
- 英語名
- Cadmium fluoride
- 分子式
- CdF2
- 分子量
- 150.41
名称と別名
CADMIUM FLUORIDE [MI]cadmium(2+);difluorideSCHEMBL662657AKOS024438113C3843カドミウムフルオリドカドミウムジフルオリドふっ化カドミウムふっ化カドミウム, 99%ふっ化カドミウム (99.98%-Cd)CdF2cadmiumfluorure
名称をさらに表示
Cadmium fluorureCADMIUM FLUORIDECadmium Flouridecadmium difluorideCadmiumfluoride,99%Cadmium fluoride≥98%cadmiumfluoride(cdf2)CADMIUM (II) FLUORIDE
データベース識別子
- CAS
7790-79-6- PubChem CID
- 10130045
- DTXSID
DTXSID6064878- UNII
- M0975E7Z8Z
- Nikkaji
- J43.716F
物性
構造計算による物性
- 極性表面積
- 0 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 2
- 回転可能結合数
- 0
- 重原子数
- 3
- 形式電荷
- 0
- 複雑度
- 0
物理化学的性質
- 融点
- 1049 °C · 1049 °C
- 沸点
- 1748 °C · 1748 °C
- 比重(密度)
- 6.33 g/mL · 6.33 g/mL at 25 °C(lit.)
- 闪点
- 1758 °C · 1758°C
- 溶解性
- soluble in acid solutions; insoluble in ethanol
- 外見
- 粉
- 比重
- 6.64 · 6.64
- 色
- 白い
- 水溶解度
- 4.3 g/100mL · 4.3g/100mL(25℃)
- 晶系
- 立方
- Merck
- 14 · 14,1619
- 空间群
- 3 m · Fm3m
- 晶格常数
- 30.539 · a/nmb/nmc/nmα/oβ/oγ/oV/nm30.5390.5390.5399090900.1564
- CAS データベース
- 7790 · 7790-79-6(CAS DataBase Reference)
- NISTの化学物質情報
- Cadmium difluoride(7790-79-6)
- EPAの化学物質情報
- Cadmium fluoride (CdF2) (7790-79-6)
化学的性質
化学的特性White powder
安全と法規制
安全と保護具
Minimum Risk LevelAcute Inhalation: 0.00003 mg/m3 (L134)
Chronic Inhalation: 0.00001 mg/m3 (L134)
Intermediate Oral: 0.0005 mg/kg/day (L134)
Chronic Oral: 0.0001 mg/kg/day (L134)
毒性情報
TreatmentCadmium poisoning is treated by removal from exposure and supportive care. If ingested, induced vomiting or gastric lavage may be performed. (L139)
Health EffectsChronic exposure to cadmium fumes can cause chemical pneumonitis, pulmonary edema, and lung diseases such as bronchitis and emphysema. Cadmium also accumulates in the kidneys, causing permanent damage. Loss of bone density also occurs. (L6)
Exposure RoutesOral (L6) ; inhalation (L6) ; dermal (L6)
Toxicity Summary
Cadmium initially binds to metallothionein and is transported to the kidney. Toxic effects are observed once the concentration of cadmium exceeds that of available metallothionein, and it has also been shown that the cadmium-metallothionein complex may be damaging. Accumulation of cadmium in the kidney results in increased excretion of vital low and high weight molecular proteins. Cadmium is a high affinity zinc analog and can interfere in its biological processes. It also binds to and activates the estrogen receptor, likely stimulating the growth of certain types of cancer cells and causing other estrogenic effects, such as reproductive dysfunction. Cadmium causes cell apoptosis by activating mitogen-activated protein kinases. (L8, A18, A19, A28)
Signs and SymptomsAcute inhalation of cadmium fumes results in metal fume fever, which is characterized by chills, fever, headache, weakness, dryness of the nose and throat, chest pain, and coughing. Ingestion of cadmium causes vomiting and diarrhea. (L6)
Carcinogen Classification1, carcinogenic to humans. (L135)
安全データ
化学と産業
薬理情報
Metabolism/Metabolites
Cadmium is absorbed from oral, inhalation, and dermal routes. Cadmium initially binds to metallothionein and albumin and is transported mainly to the kidney and liver. Toxic effects are observed once the concentration of cadmium exceeds that of available metallothionein, and it has also been shown that the cadmium-metallothionein complex may be damaging. Cadmium is not known to undergo any direct metabolic conversion and is excreted unchanged, mainly in the urine. (L6)
用途と製造
UsesCadmium fluoride is used in the production of metallic alloys, for electronic and optical applications and as a starting material for laser crystals. (L467)
応用分野
解説CdF2(150.41)．金属カドミウムまたはカドミウムの酸化物，硫化物，塩化物などにフッ素を反応させると得られる．白色の粉末．等軸晶系．密度6.33 g cm－3．融点1100 ℃，沸点1748 ℃．水，フッ化水素酸，鉱酸に可溶，エタノールに不溶．ガラスの製造，半導体素子・光学装置・レーザー結晶の原料などに用いられる．[CAS 7790-79-6]森北出版「化学辞典（第2版）
用途研究用途、発行スクリーン用途の蛍光剤
使用Cadmium fluoride is used in phosphors, glass and nuclear reactor controls. It is also used in high-temperature lubricants and to start crystals for lasers. It is used in oxygen-sensitive applications such as the production of metallic alloys and it is also used in limited medical treatment protocols. In addition, it can be used in synthetic organic chemistry.
調製方法
製造方法Cadmium fluoride is prepared by the reaction of gaseous fluorine or hydrogen fluoride with cadmium metal or its salt, such as chloride, oxide or sulfide:Cd + F2 → CdF2Cd + 2HF → CdF2 + H2CdO + 2HF → CdF2 + H2OIt also may be obtained by dissolving cadmium carbonate in 40% hydrofluoric acid solution, evaporating the solution and drying in vacuum at 150°C:CdCO3 + 2HF → CdF2 + H2O + CO2It also may be prepared by mixing cadmium chloride and ammonium fluoride solutions, followed by crystallization.
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