メチルマグネシウムヨージド (33%エチルエーテル溶液, 約2mol/L)

Iodomethylmagnesium

HCID 101907CAS 917-64-6

部分構造検索類似構造を探す

基本情報

標準SMILES: [CH3-].[I-].[Mg+2]
InChIKey: AUPXBVDHVRZMIB-UHFFFAOYSA-M
分子式: CH3IMg
平均分子量: 166.24 g/mol

名称と識別子

優先名称: Iodomethylmagnesium
IUPAC: magnesium;carbanide;iodide
現地名: メチルマグネシウムヨージド (33%エチルエーテル溶液, 約2mol/L)
英語名: Methylmagnesium iodide
分子式: CH3IMg
分子量: 166.24

名称と別名

Methylmagnesium Iodide917-64-6IodomethylmagnesiumMagnesium, iodomethyl-EINECS 213-031-1DTXSID301015526RefChem:791164DTXCID801473791213-031-1methyl magnesium iodidemethylmagnesiumiodideMeMgI

名称をさらに表示

メチルマグネシウムヨージド (33%エチルエーテル溶液, 約2mol/L)メチルマグネシウムヨージドメチルヨードマグネシウムよう化メチルマグネシウム,ジエチルエーテル溶液メチルマグネシウムヨージド・ジエチルエーテル溶液(約1MOL/L)メチルマグネシウムヨージド溶液CHLOROMETHYLMAGNESIUMMethylmagnesium iodide solutionnesium iodideiodomethyl-magnesiuMethyliodomagnesiumMethylmagnesium iodine3.0 M in diethyl ether

CH3MgImethyl-magnesium iodideIodido(methyl)magnesium(methyl)magnesium iodideSCHEMBL1072(Methyl-d3)magnesium iodideAUPXBVDHVRZMIB-UHFFFAOYSA-MMethylmagnesium iodide 1M in THF

データベース識別子

CAS: 917-64-6
PubChem CID: 101907
DTXSID: DTXSID301015526
EC Number: 213-031-1

物性

構造計算による物性

極性表面積: 0 Å²
水素結合供与体数: 0
水素結合受容体数: 2
回転可能結合数: 0
重原子数: 3
形式電荷: 0
複雑度: 4.8

物理化学的性質

沸点: 35 °C · 35.00°C
比重(密度): 1.26 g/mL · 1.26 g/mL at 20 °C
闪点: -40 °C · -40 °C
BRN: 1209226 · 1209226
InChI: InChI=1S/CH3.HI.Mg/h1H3;1H;/q;;+1/p-1
InChIKey: AUPXBVDHVRZMIB-UHFFFAOYSA-M
SMILES: [Mg](I)C
EPAの化学物質情報: Magnesium, iodomethyl- (917-64-6)

化学的性質

化学的特性Dark grey liquid

安全と法規制

GHS分類

GHS Classification · 4 件

Danger

H260 (88.9%): In contact with water releases flammable gases which may ignite spontaneously [Danger Substances and mixtures which in contact with water, emit flammable gases]

P223, P231+P232, P260, P264, P280, P301+P330+P331, P302+P335+P334, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P402+P404, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 45 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Hazard Classes and CategoriesWater-react. 1 (88.9%)

安全データ

F: 1-3-10
wgk: 1
tsca: TSCA listed
ridadr: UN 3399 4.3/PG 1
hs_code: 29319090
risk_code: 12-14/15-22-34-66-67-19-11
安衛法: 有機則第二種有機溶剤等
消防法: 危-4-特-I
hazard_code: F+,C,F
safety_code: 16-26-36/37/39-43-45-7/8
hazard_class: 4.2
packing_group: I
Hazard Classifications: Eye Dam. 1Flam. Liq. 1Skin Corr. 1BSTOT SE 3Water-react 1
ストレージクラス: 4.3 - Hazardous materials which set free flammable gases upon contact with water

化学と産業

用途と製造

General Manufacturing InformationMagnesium, iodomethyl-: ACTIVE

応用分野 · 1 件

使用Methylmagnesium iodide solution can be used: To prepare cis-1,2-dialkylcyclopropanols by treating with titanium(IV) alkoxide and carboxylic esters. In stereospecific Ni catalyzed Kumada cross-coupling reactions of benzylic ethers. To prepare 2,4-disubstituted selenochromenes by reacting with 1-benzoselenopyrylium salts. In one of the key synthetic steps for the preparation of 7β-methyl-substituted 5-androstene derivatives from 3β-acetoxyandrost-5-en-17-one stereoselectively.

上流・下流製品情報

下流製品

サプライヤー50 社

阿诺西（上海）生物技术有限公司400-1107768 15058188853 · [email protected]

湖北永阔科技有限公司027-59223108 15972152991 · [email protected]

湖北万得化工有限公司15377098680 15377098680 · [email protected]

郑州鸿晟医药科技有限公司0371-55695890 15637198702 · [email protected]

Syntechem Co.,Ltd[email protected]

補足説明

定義Available as solution inether.