基本情報
- 標準SMILES
CC(C)C1=CC2=CC[C@@H]3[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1- InChIKey
RSWGJHLUYNHPMX-ONCXSQPRSA-N- 分子式
- C20H30O2
- 平均分子量
- 302.5 g/mol
- 単同位体質量
- 302.2245802
名称と識別子
- 優先名称
- Abietic Acid
- IUPAC
- (1R,4aR,4bR,10aR)-1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid
- 現地名
- ロジン
- 英語名
- Rosin
- 分子式
- C19H29COOH
- 分子量
- 0
名称と別名
名称をさらに表示
データベース識別子
- CAS
15522-12-0、514-10-3、8050-09-7- PubChem CID
- 10569
- DTXSID
DTXSID7022047- ChEMBL
CHEMBL71893- ChEBI
CHEBI:28987- UNII
- V3DHX33184
- EC Number
- 208-178-3
- Nikkaji
- J10.135D
物性
構造計算による物性
- XLogP
- 4.8
- 極性表面積
- 37.3 Ų
- 水素結合供与体数
- 1
- 水素結合受容体数
- 2
- 回転可能結合数
- 2
- 重原子数
- 22
- 形式電荷
- 0
- 複雑度
- 542
実験および物理化学的性質
Physical Description
Yellowish resinous powder. (NTP, 1992)
Yellow solid; [Hawley] Colorless crystalline solid; [MSDSonline]
物理化学的性質
- 融点
- 70 · 70-72°C
- 比重(密度)
- 1 · 1,07 g/cm3
- 闪点
- 180 °C · 180°C
- 貯蔵温度
- Room Temperature
- 溶解性
- 0.1 g/mL、透明、強い黄色 · クロロホルム: 0.1 g/mL、透明、強い黄色
- 外見
- 粉体・固形
- 色
- ダークイエロー
- 比重
- 1.07 · 1.07~1.08
- 臭い (Odor)
- 100 · 100.00?%で。マイルドなバルサミコウッディ
- 水溶解度
- アルコール、ベンゼン、エーテルに可溶。水に不溶
- Merck
- 14 · 14,8266
- Dielectric constant
- 2.5 · 2.5(Ambient)
- 安定性
- 安定。可燃性。酸化剤と相容れない。
- 化粧品成分の機能
- 脱毛剤フィルム形成バインディング粘度制御
- InChI
- 1S/C20H30O2/c1-13(2)14-6-8-16-15(12-14)7-9-17-19(16,3)10-5-11-20(17,4)18(21)22/h7,12-13,16-17H,5-6,8-11H2,1-4H3,(H,21,22)/t16-,17+,19+,20+/m0/s1
- InChIKey
- RSWGJHLUYNHPMX-ONCXSQPRSA-N
- SMILES
- OC(=O)[C@]1([C@H]2[C@@]([C@H]3CCC(=CC3=CC2)C(C)C)(CCC1)C)C
- LogP
- 13.11 · 13.110 (est)
- CAS データベース
- 8050 · 8050-09-7
- EPAの化学物質情報
- Rosin (8050-09-7)
化学的性質
化学的特性solid with a slight odour of turpentine
化学性质天然樹脂で,アルキド樹脂の変性剤として用いられる。
安全と法規制
GHS分類
GHS Classification
This chemical does not meet GHS hazard criteria for 60.6% (134 of 221) of all reports.
Warning
H315 (38.9%): Causes skin irritation [Warning Skin corrosion/irritation];H319 (38.9%): Causes serious eye irritation [Warning Serious eye damage/eye irritation];H335 (38.5%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation];H400 (25.3%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]
P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 221 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Reported as not meeting GHS hazard criteria per 134 of 221 reports by companies.;There are 9 notifications provided by 87 of 221 reports by companies with hazard statement code(s).;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
危険有害性情報
Regulatory Information
Chemical: 1-Phenanthrenecarboxylic acid, 1,2,3,4,4a,4b,5,6,10,10a-decahydro-1,4a-dimethyl-7-(1-methylethyl)-, [1R-(1.alpha.,4a.beta.,4b.alpha.,10a.alpha.)]-
1-Phenanthrenecarboxylic acid, 1,2,3,4,4a,4b,5,6,10,10a-decahydro-1,4a-dimethyl-7-(1-methylethyl)-, (1R,4aR,4bR,10aR)-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
Reactivity Profile
ABIETIC ACID reacts exothermically with bases, both organic (for example, the amines) and inorganic. Can react with active metals to form gaseous hydrogen and a metal salt. Such reactions are slow if the solid acid remains dry. Can react with cyanide salts to generate gaseous hydrogen cyanide. The reaction is slow for dry, solid carboxylic acids. Insoluble carboxylic acids react with solutions of cyanides to cause the release of gaseous hydrogen cyanide. Flammable and/or toxic gases and heat are generated by the reaction of carboxylic acids with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides. Carboxylic acids, especially in aqueous solution, also react with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), to generate flammable and/or toxic gases and heat. Their reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat. Like other organic compounds, carboxylic acids can be oxidized by strong oxidizing agents and reduced by strong reducing agents. These reactions generate heat. A wide variety of products is possible. Like other acids, carboxylic acids may initiate polymerization reactions; like other acids, they often catalyze (increase the rate of) chemical reactions.
安全と保護具
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.;SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.;INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.;INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)
Nonfire Spill Response
SMALL SPILLS AND LEAKAGE: If you spill this chemical, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with alcohol followed by washing with a strong soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.;STORAGE PRECAUTIONS: You should store this material in a refrigerator. (NTP, 1992)
Personal Protective Equipment (PPE)
RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter.;RECOMMENDED GLOVE MATERIALS: Permeation data indicate that butyl rubber gloves may provide protection to contact with this compound. Butyl rubber over latex gloves is recommended. However, if this chemical makes direct contact with your gloves, or if a tear, hole or puncture develops, remove them at once. (NTP, 1992)
毒性情報
法規制情報
Regulatory Information
Chemical: 1-Phenanthrenecarboxylic acid, 1,2,3,4,4a,4b,5,6,10,10a-decahydro-1,4a-dimethyl-7-(1-methylethyl)-, [1R-(1.alpha.,4a.beta.,4b.alpha.,10a.alpha.)]-
1-Phenanthrenecarboxylic acid, 1,2,3,4,4a,4b,5,6,10,10a-decahydro-1,4a-dimethyl-7-(1-methylethyl)-, (1R,4aR,4bR,10aR)-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
安全データ
- F
- 10-21
- wgk
- 1
- tsca
- TSCA listed
- rtecs
- VL0480000
- hs_code
- 38061010
- risk_code
- 43
- 安衛法
- 57,57-2
- hazard_code
- Xi
- safety_code
- 24-37
- Hazard Classifications
- Skin Sens. 1
- ストレージクラス
- 11 - Combustible Solids
化学と産業
薬理情報
MeSH Pharmacological Classification
Fibrinolysin or agents that convert plasminogen to FIBRINOLYSIN.
Substances that eliminate free radicals. Among other effects, they protect PANCREATIC ISLETS against damage by CYTOKINES and prevent myocardial and pulmonary REPERFUSION INJURY.
用途と製造
Uses
Used to make ester gums in lacquers, varnishes, and soaps; Also used in metal resinates, plastics, and paper sizes; [Merck Index]
Pulp and Paper Processing [Category: Industry]
応用分野
解説ロジンはい天然樹脂の一種で、松脂(まつやに)とよばれるものにはロジンが多い。マツの樹皮からとったバルサム(生(なま)松脂のテレビン油。テレピン油ともいう)を水蒸気蒸留してまず15~20%のテレビン油を除き、残りの水分を蒸発させ、溶融して得られた樹脂である。主成分はC20H30O2のアビエチン酸類やピマル酸類などの混合物である。もろく耐熱性はよくないが安価のため、ワニス、接着剤、ベルトの滑り止め、洗濯せっけんの配合剤、紙のサイジング剤その他に広く使われている。[垣内 弘][参照項目] | テレビン油 | バルサム | 松脂小学館 日本大百科全書(ニッポニカ) )
用途塗料原料、インキ、ゴム接着剤、石けん、染料、皮靴
用途製紙用サイズ、ワニス、印刷インキ、殺虫剤など
使用Rosin is a yellow resin in the production of varnishes, printing inks, paper, soldering fluxes, greases, cutting fluids, glue tackifiers, adhesives, surface coatings, polish, insulations, waxes, cosmetics (mascara, rouge, eye shadow), topical medicaments, shoes, violin bow rosin, day, athletic grip aid, pine-oil cleansers; component in dental impression materials and periodontal packings.
一般的な説明Gum rosin is an exudate gum, which is extracted from pine trees.
使用用途ロジンはスポーツ時のすべり止めとして使われている他、各種工業用の中間素材としても活用されています。また、ロジンを原料として製造されるロジン誘導体は、製紙用薬品、合成ゴム、インキ、塗料、はんだ、粘着・接着剤さらにはチューイングガム等に幅広く使用されています。 1. サイズ剤 (インキのにじみ止め) 製紙会社が紙を製造する過程で、紙に書いたインクがにじんで広がってしまうのを防ぐ目的で使用されるのが製紙用サイズ剤です。水系で紙に均一に浸透するサイズ剤として、ロジン誘導体が使われています。 2. 粘着・接着剤用樹脂 粘着・接着剤の粘着力の発現や各種基材への密着性を向上するために使用されるのが、粘着付与剤 (タッキファイヤー) です。粘着付与剤にはロジン誘導体や水素化石油樹脂などがあり、粘着・接着剤の主成分であるエラストマーや合成樹脂などに幅広く相溶性を示すのがロジン誘導体の特徴です。 3. 印刷インキ用樹脂 印刷物をキレイに仕上げるための色を表現する顔料の分散性を良くし、印刷時の乾燥性 (生産性) を向上するために使用されるのが印刷インキ用樹脂です。主にオフセット印刷に使用されるインキ用樹脂としてロジン変性フェノール樹脂が使われています。 4. 合成ゴム重合用乳化剤 自動車のタイヤ用などをはじめ SBR (スチレンブタジエンゴム) 、ABS (アクリロニトリル・ブタジエンゴム・スチレン樹脂) 、CR (クロロプレンゴム) 等の合成ゴム類の重合用乳化剤として、粘着性付与やゴムの諸物性の向上の役割を果たすために主に不均化ロジンソープ (アルカリ金属塩の水溶液) が使用されています。 5. はんだフラックス樹脂 フラックスは、はんだ付けされる基板電極や部品、はんだ自身の金属酸化膜を除去して清浄な表面を作り出します。このことで、はんだのぬれ性を十分に確保し、はんだの付きを良くします。このフラックスにロジン誘導体が含まれています。 6. チューインガムベース チューインガムの噛み心地の度合いを調整しているのが、ロジンを原料とした食品用「エステルガム」です。安全な食品添加物として登録され、粒ガム・板ガムを問わず広く添加されています。
上流・下流製品情報
上流原料
下流製品
サプライヤー50 社
補足説明
定義本品は、Pinaceae(マツ属)の分泌物から精油をのぞいて得た固形の樹脂である。
定義A brittle yellow or brown resin that remains after the distillation of turpentine. It is used as a flux in soldering and in making paints and varnishes. Powdered rosin gives a ‘grip’ to violin bows and boxers’ shoes.
関連反応
関連ノート
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