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[1,1'-ビフェニル]-4,4'-ジアミン·2塩酸塩
ベンジジン·2塩酸塩 · 4,4'-ビフェニルジアミン·二塩酸塩 · ベンジジン·二塩酸塩 · [1,1'-ビフェニル]-4,4'-ジアミン·2塩酸塩 · ベンジジン塩酸塩 · ベンジジンエンサンエン · ベンジジン二塩酸塩 · BENZIDINE HYDROCHLORIDE
![[1,1'-ビフェニル]-4,4'-ジアミン·2塩酸塩 の分子構造式](/img/chemical/10754.png)
識別子と物理属性
| CAS No. | 531-85-1 |
|---|---|
| 分子式 | C12H12N2.2ClH |
| 平均分子量 | 257.16 g/mol |
| 単同位体質量 | 256.0534038 g/mol |
| SMILES | Cl.Cl.Nc1ccc(-c2ccc(N)cc2)cc1 |
| InChIKey | RUAXWVDEYJEWRY-UHFFFAOYSA-N |
| PubChem CID | 10754 |
| ChEMBL | CHEMBL3184470 |
| EC No. | 208-519-6 |
| DTXSID | DTXSID7020138 |
| 現地名 | [1,1'-ビフェニル]-4,4'-ジアミン·2塩酸塩 |
化学・物理的性質
| 極性表面積 | 52 |
|---|---|
| 水素結合供与体数 | 4 |
| 水素結合受容体数 | 2 |
| 回転可能結合数 | 1 |
| 重原子数 | 16 |
| 形式電荷 | 0 |
| 複雑度 | 145 |
| 物質分類 | Nitrogen Compounds -> Benzidine and DerivativesCarcinogens |
| 溶解度 | 1 to 5 mg/mL at 74.3 °F (NTP, 1992)23.5℃で0.1～0.5g/100mL |
| 融点 | greater than 572 °F (NTP, 1992)≥300 °C |
| 蒸気圧 | 0.00000438 [mmHg] |
| Physical Description | Benzidine dihydrochloride is a white crystalline powder. (NTP, 1992)White solid[CAMEO] Colorless crystalline solid[MSDSonline] |
| 外観・状態 | powder |
| 色 | リーフレット |
| BRN | 3914846 |
| InChI | InChI=1S/C12H12N2.ClH/c13-11-5-1-9(2-6-11)10-3-7-12(14)8-4-10/h1-8H,13-14H21H |
| InChIKey | FYRTZXXTIDKEJD-UHFFFAOYSA-N |
| SMILES | NC1C=CC(C2C=CC(N)=CC=2)=CC=1.Cl |
| CAS データベース | 531-85-1(CAS DataBase Reference) |
| EPAの化学物質情報 | Benzidine dihydrochloride (531-85-1) |
安全性と法規制
| GHS 分類 | DangerH302: Harmful if swallowed [Warning Acute toxicity, oral]P203, P264, P270, P273, P280, P301+P317, P318, P330, P391, P405, and P501 (click each P-code to see the statement)H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral] |
|---|---|
| 規制情報 | Hazard Traits - CarcinogenicityS - indicates a substance that is identified in a final Significant New Use Rule.[1,1'-Biphenyl]-4,4'-diamine, dihydrochloride: Does not have an individual approval but may be used under an appropriate group standardThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.) |
| 火災危険 | Flash point data for this chemical are not availablehowever, it is probably combustible. (NTP, 1992) |
| 健康有害性 | SYMPTOMS: Symptoms of exposure to this compound include nausea, vomiting, liver damage and kidney damage. |
| 有害性の概要 | Readily absorbed through skinSymptoms of exposure to this compound include nausea, vomiting, liver damage and kidney damage. [CAMEO] May cause irritationTargets the liver, kidneys, and bladder[MSDSonline] See Benzidine. |
| 反応性グループ | Salts, Acidic |
| Reactivity Profile | Acidic organic/inorganic salts, such as BENZIDINE DIHYDROCHLORIDE, are generally soluble in water. The resulting solutions contain moderate to high concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions. |
| Air and Water Reactions | This chemical may be sensitive to prolonged exposure to light and air. Slightly soluble in water. |
| Hazard Classes and Categories | Acute Tox. 4 (100%)Carcinogenicity - category 1A |
用途
一般的な説明
White crystalline powder.
製法・合成法
純化方法
Benzidine dihydrochloride [531-85-1] M 257.2, m >250o(dec). Crystallise the salt by dissolving in hot H2O, and adding conc HCl to the slightly cooled solution. CARCINOGENIC.[Beilstein 13 IV 365.]