2,4-ジアミノアゾベンゼン·塩酸塩

C.I. Basic Orange 2

HCID 10771

基本情報

CAS
532-82-1
標準SMILES
Cl.Nc1ccc(N=Nc2ccccc2)c(N)c1
InChIKey
MCTQNEBFZMBRSQ-UHFFFAOYSA-N
分子式
C12H12N4.ClH
平均分子量
248.71 g/mol
単同位体質量
248.0828741

概要

C.i. basic orange 2 appears as red-brown powder, large black shiny crystals with a green luster or purple powder. (NTP, 1992)

名称と識別子

優先名称
C.I. Basic Orange 2
IUPAC
4-phenyldiazenylbenzene-1,3-diamine;hydrochloride
現地名
2,4-ジアミノアゾベンゼン·塩酸塩
英語名
Basic Orange 2
分子式
C12H12N4.ClH
分子量
248.71

名称と別名

C.I. Basic Orange 2DTXSID0024559DTXCID8032413RefChem:1080553Chrysoidine532-82-1Basic Orange 2Chrysoidine GChrysoidine YChrysoidinChrysoidin YChrysoidine Orange
名称をさらに表示
2,4-ジアミノアゾベンゼン·塩酸塩クリソイジンY4-(フェニルアゾ)-1,3-ベンゼンジアミン·塩酸塩クリソイジンGクリソイジン4-フェニルアゾ-m-フェニレンジアミン塩酸塩C.I.ベーシックオレンジ22,4-ジアミノアゾベンゼン塩酸塩クリソイジン G4-フェニルアゾ-m-フェニレンジアミン一塩酸塩ベーシックオレンジ2標準品ChrCI 11270Ke Yi setOrange redChrysodineCI NO 11270
Chrysoidine yghChrysoidine AChrysoidine BChrysoidine JChrysoidine MTertrophene Brown CG2,4-Diaminoazobenzene hydrochlorideChrysoidine GN

データベース識別子

CAS
532-82-1
PubChem CID
10771
DTXSID
DTXSID0024559
ChEMBL
CHEMBL1524085
ChEBI
CHEBI:82424
UNII
2431787HMZ

物性

構造計算による物性

極性表面積
76.8 Ų
水素結合供与体数
3
水素結合受容体数
4
回転可能結合数
2
重原子数
17

実験および物理化学的性質

CosmeticsHair dyeing
Solubility1 to 10 mg/mL at 73 °F (NTP, 1992)
Melting Point244 to 245 °F (NTP, 1992)
Physical DescriptionC.i. basic orange 2 appears as red-brown powder, large black shiny crystals with a green luster or purple powder. (NTP, 1992)

物理化学的性質

融点
235 °C · 235 °C (dec.)(lit.)
沸点
2262 °C · 2262°C
比重(密度)
1.2171 · 1.2171 (rough estimate)
屈折率
1.611 · 1.6110 (estimate)
貯蔵温度
room temp
溶解性
水、エタノール、アセトン、メチルセロソルブ、キシレンに可溶、イソベンゼンにほとんど溶けない

化学的性質

化学的特性BORDEAUX TO DEEP PURPLE CRYSTALLINE POWDER

安全と法規制

危険有害性情報

Fire HazardsFlash point data for this chemical are not available. It is probably combustible. (NTP, 1992)
Health HazardsSYMPTOMS: This compound may cause irritation.
Reactive GroupAzo, Diazo, Azido, Hydrazine, and Azide Compounds
Reactivity AlertsExplosive
Reactivity Profile · 1 件

C.I. BASIC ORANGE 2 is an azo compound. Toxic gases are formed by mixing compounds containing azo groups with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides. This chemical is incompatible with strong oxidizing agents. (NTP, 1992)

Air and Water ReactionsAzo dyes can be explosive when suspended in air at specific concentrations. Slightly soluble in water.

安全と保護具

Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. A water spray may also be used. (NTP, 1992)
First Aid · 1 件

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1 件

SMALL SPILLS AND LEAKAGE: If you spill this chemical, you should dampen the solid spill material with water, then transfer the dampened material to a suitable container. Use absorbent paper dampened with water to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Wash all contaminated surfaces with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Personal Protective Equipment (PPE) · 1 件

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

安全データ

wgk
2
tsca
TSCA listed
rtecs
ST3380000
ridadr
UN 3077 9/PG 3
毒性
mma-sat 50 mg/plate MUREAV 44,9,77
hs_code
32129000

化学と産業

用途と製造

Use ClassificationCosmetics -> Hair dyeing
応用分野 · 3 件

用途皮革、紙の染色。遊離塩基の形でロウ、プラスチックの着色に使用。

使用Orange dye for cotton and silk.

一般的な説明Red-brown powder, large black shiny crystals with a green luster or purple powder.

調製方法 · 1 件

純化方法It is a red-brown powder which is recrystallised from H2O. It gives a yellow solution in conc H2SO4 which turns orange on dilution. Its solubility at 15o is 5.5% (H2O), 4.75% (EtOH), 6.0% (cellosolve), 9.5% (ethylene glycol), 0.005% (xylene) and is insoluble in *C6H6. The hydroiodide has m 184o (from EtOH) and the picrate forms red needles m 196o. [Muramatsu Bull Chem Soc Jpn 31 864 1958, Beilstein 6 IV 561.]

サプライヤー100 社

国药集团化学试剂有限公司86-21-63210123 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
湖南韵邦生物科技股份有限公司85561037 15386497078 · [email protected]
湖北万得化工有限公司15377098680 15377098680 · [email protected]

補足説明

定義A dye made from aniline.

関連反応

1 件

化合物ノート

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