556-88-7NC(N)=N[N+](=O)[O-]IDCPFAYURAQKDZ-UHFFFAOYSA-N2-nitroguanidine is a nitroguanidine and a one-carbon compound. It is a tautomer of a 1-nitroguanidine.
556-88-7安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。
解説ニトログアニジン,針状晶.分解点257 ℃.d4 1.775.λmax 264 nm(log ε 4.16).発火点275 ℃.爆発熱4.43 kJ g-1(溶液).熱湯,DMF,硫酸に可溶,エタノール,硝酸に難溶.ニトラミン系爆薬で,固体ロケット推進薬として重要である.医薬品の合成中間体である.頭痛,低血圧などの薬害を起こす.
用途火薬、爆薬
使用Nitroguanidine is used in the prediction of heats of detonation of energetic compounds from their molecular structure. It is also used in the synthetic preparation of imidacloprid-d4 (I274992), which is a neonicotinoid. Reactant involved in the synthesis of: 1,5-Disubstituted-1,3,5-hexahydrotriazine-2-(N-nitro)imines with insecticidal activityHexahydrotriazine-N-nitroimine analogs with insecticidal activity via Mannich reactions Reactant involved in: The study of the effects of vessel materials on exothermic decomposition energyNitration of arenesNitration of (nitrimino)tetrahyrdooxadiazine and (nitrimino)hexahydrotriazine
一般的な説明Nitroguanidine is shipped as a slurry or wet mass of pale yellow crystals. If Nitroguanidine should dry out Nitroguanidine can explode due to shock, heat, flame, or friction. The primary hazard is blast where the entire load can explode instantaneously and not from flying projectiles and fragments. Under prolonged exposure to fire or heat they can explode.
純化方法Crystallise it from water (20mL/g). The nitrate has m 147o(dec)( prisms, H2O). [Beilstein 3 H 126, 3 III 236.]
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CHEBI:39181化学的特性Nitroguanidine is a white powder, It is a well known explosive substance which is used both in high ex plosives and in propellent powders. As a high explosive it is about as powerful as trinitrotoluene and has been used in various mixtures, with ammonium nitrate, paraffin, etc., in bombs and for other purposes where an insensitivir and powerful high explosive is needed. It has the further advantage of be ing exceptionally cool. The experiments of Vieille showed that this explosive produces a temperature of only 907 C. Its coolness commends it for use in safety explosives. If incorporated into nitrocellulose powder it renders the powder flashless without impair ing its ballistic power, and, as Vieille showed, reduces erosion and lengthens the accuracy life of the gun.