CAS 13569-65-8 Rhodium chloride trihydrate (HCID 11459718)

基本情報

CAS: 13569-65-8
標準SMILES: O.O.O.[Cl][Rh]([Cl])[Cl]
InChIKey: TYLYVJBCMQFRCB-UHFFFAOYSA-K
分子式: Cl3H6O3Rh
平均分子量: 263.31 g/mol
単同位体質量: 261.84375

名称と識別子

優先名称: Rhodium chloride trihydrate
IUPAC: trichlororhodium;trihydrate
英語名: Rhodium (III) chloride trihydrate
分子式: Cl3H6O3Rh
分子量: 263.31

名称と別名

Rhodium(III) chloride trihydrateRhodium chloride trihydrateRefChem:883009Rhodium (III) chloride, trihydrateRhodium (III) chloride, hydrateRhodium chloride (RhCl3), trihydrateRhodium chloride, trihydrate13569-65-8Rhodium (III) chloride trihydratetrichlororhodium;trihydrateH6Cl3O3RhSCHEMBL16444

名称をさらに表示

RHODIUM CHLORIDEchloride trihydratetrichlororhodium trihydrateRHODIUM TRICHLORIDE TRIHYDRATETriaquatrichlororhodiumRHODIUM CHLORIDE, HYDROUSRHODIUM TRICHLORIDE, HYDRATERhodiumTrichlorideForSynthesisRhodium (III) chloride solution

rhodium(III)-chloride trihydrateDTXSID90929110Trichloridorhodium--water (1/3)AKOS015964084AC-18130Rhodium(3+) chloride--water (1/3/3)

データベース識別子

CAS: 13569-65-8、13876-89-6
PubChem CID: 11459718
DTXSID: DTXSID90929110

物性

構造計算による物性

極性表面積: 3 Å²
水素結合供与体数: 3
水素結合受容体数: 3
回転可能結合数: 0
重原子数: 7
形式電荷: 0
複雑度: 8

実験および物理化学的性質

DensityRelative density (water = 1): >1

SolubilitySolubility in water: soluble

Decomposition100 °C

Physical Description · 2 件

Red deliquescent solid; [ICSC] Dark red odorless crystals; Soluble in water; [BASF MSDS]

RED DELIQUESCENT POWDER.

物理化学的性質

Melting point: 100 °C · 100 °C (decomp)
Density: 1 g/cm3 · 1 g/cm3
storage temp.: Sealed in dry,Room Temperature
Appearance: Reddish brown to black Solid
InChI: InChI=1S/3ClH.H2O.Rh/h3*1H;1H2;/q;;;;+3/p-3
InChIKey: HSSMNYDDDSNUKH-UHFFFAOYSA-K
SMILES: [Rh](Cl)(Cl)Cl.O
CAS DataBase Reference: 13569 · 13569-65-8(CAS DataBase Reference)
FDA UNII: 4 D88MX3Z8 · Q4D88MX3Z8
Symbol(GHS): 7 · GHS07
Signal word

安全と法規制

GHS分類

GHS Classification · 5 件

Danger

H290 (97.2%): May be corrosive to metals [Warning Corrosive to Metals]；H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]；H318 (100%): Causes serious eye damage [Danger Serious eye damage/eye irritation]；H341 (96.3%): Suspected of causing genetic defects [Warning Germ cell mutagenicity]；H400 (95.4%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]；H410 (95.4%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]

P203, P234, P264, P264+P265, P270, P273, P280, P301+P317, P305+P354+P338, P317, P318, P330, P390, P391, P405, P406, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 109 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Regulatory InformationRhodium chloride (RhCl3), trihydrate: Does not have an individual approval but may be used under an appropriate group standard

Fire HazardsNot combustible. Gives off irritating or toxic fumes (or gases) in a fire. See Chemical dangers

Hazards SummaryIntraperitoneal LD50 (mouse) = 369 mg/kg; [RTECS] No listed effects of short-term or long-term exposure; [ICSC] An irritant that may cause burns; May cause skin sensitization; [BASF MSDS] See Rhodium chloride.

UN ClassificationUN Hazard Class: 8; UN Pack Group: III

Chemical DangersDecomposes on heating. This produces toxic and corrosive fumes including hydrogen chloride (see ICSC 0163). This generates toxic hazard. Reacts violently with iron pentacarbonyl and zinc. This generates explosion hazard.

化学と産業

用途と製造

UsesUsed as a catalyst for the conversion of methane to acetic acid; [ExPub: Health Council of the Netherlands]

応用分野 · 1 件

DescriptionRhodium trichloride is an odourless, red-brown to black crystalline powder. It is corrosive to steel and aluminium. It is hygroscopic and absorbs moisture or water from the air. It is incompatible with strong oxidising agents. On decomposition, rhodium trichloride emits hydrogen chloride, carbon monoxide, carbon dioxide, and rhodium/rhodium oxides.