基本情報
- CAS
587-85-9- 標準SMILES
c1cc[c]([Hg][c]2ccccc2)cc1- InChIKey
HWMTUNCVVYPZHZ-UHFFFAOYSA-N- 分子式
- C12H10Hg
- 平均分子量
- 354.8 g/mol
- 単同位体質量
- 356.048894
名称と識別子
- 優先名称
- Diphenylmercury
- IUPAC
- diphenylmercury
- 現地名
- ジフェニル水銀(II)
- 英語名
- Diphenylmercury
- 分子式
- C12H10Hg
- 分子量
- 354.8
名称と別名
DIPHENYLMERCURY587-85-9Mercury, diphenyl-Diphenylmercury(II)Benzene, mercuriodi-DifenylrtutDifenylrtut [Czech]DTXSID3042130EINECS 209-606-19JF9FUI57JNSC 23990BRN 0637234
名称をさらに表示
ジフェニル水銀(II)ジフェニル水銀ジフエニル水ジフェニル水銀(Ⅱ)diphenylmercurediphenyl-mercurMERCURY DIPHENYLmercury(ii)diphenylDiphenylmercury,min.96%Diphenylmercury, min. 96%
AI3-17856NSC-23990DTXCID10221304-16-00-01702 (Beilstein Handbook Reference)Mercury, diphenylBenzene, mercuriodiRefChem:588915209-606-1
データベース識別子
- CAS
587-85-9- PubChem CID
- 11488
- DTXSID
DTXSID3042130- UNII
- 9JF9FUI57J
- EC Number
- 209-606-1
- Nikkaji
- J37.005C
物性
構造計算による物性
- 極性表面積
- 0 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 0
- 回転可能結合数
- 2
- 重原子数
- 13
- 形式電荷
- 0
- 複雑度
- 116
実験および物理化学的性質
Chemical ClassesMetals -> Metals, Organic Compounds
Density2.318 @25 °C
Physical DescriptionWhite crystalline solid; Insoluble in water; [Alfa Aesar MSDS]
物理化学的性質
- 融点
- 121 · 121-124 °C (lit.)
- 沸点
- 306 °C · >306°C
- 比重(密度)
- 2.32 g/mL · 2.32 g/mL at 25 °C (lit.)
- 闪点
- 306 °C · >306°C
- 貯蔵温度
- Poison room
- 外見
- 粉末
- 色
- 白色
- 水溶解度
- 水に不溶。
- BRN
- 637234 · 637234
- Henry's Law Constant
- 2.8 · 2.8×102 mol/(m3Pa) at 25℃, Abraham et al. (2008)
- InChI
- 1S/2C6H5.Hg/c2*1-2-4-6-5-3-1;/h2*1-5H;
- InChIKey
- HWMTUNCVVYPZHZ-UHFFFAOYSA-N
- SMILES
- [Hg](c1ccccc1)c2ccccc2
- CAS データベース
- 587 · 587-85-9(CAS DataBase Reference)
- EPAの化学物質情報
- Mercury, diphenyl- (587-85-9)
化学的性質
化学的特性White to beige powder
安全と法規制
安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。
GHS分類
GHS Classification
Danger
H300 (100%): Fatal if swallowed [Danger Acute toxicity, oral]
P260, P262, P264, P270, P271, P273, P280, P284, P301+P316, P302+P352, P304+P340, P316, P319, P320, P321, P330, P361+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 46 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
危険有害性情報
Regulatory InformationMercury, diphenyl-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
Hazards Summary
Causes altered sleep time (including change in righting reflex) and ataxia in intraperitoneal lethal-dose studies of mice; [RTECS] An irritant; Highly toxic by ingestion, inhalation, and skin absorption; [Alfa Aesar MSDS] See Mercury, aryl compounds and linked occupational diseases.
Hazard Classes and CategoriesAcute Tox. 2 (100%)
安全と保護具
Threshold Limit Values (TLV)0.1 [mg/m3], as Hg
Permissible Exposure Limit (PEL)0.1 [mg/m3], as Hg
Protective Action Criteria (PAC)
2.0 [mg/m3]
22 [mg/m3]
130 [mg/m3]
Immediately Dangerous to Life or Health (IDLH)10.0 [mg/m3], as Hg
毒性情報
Adverse EffectsNeurotoxin - Sensorimotor
安全データ
- wgk
- 3
- tsca
- TSCA listed
- rtecs
- OW3150000
- ridadr
- UN 2026 6.1/PG 3
- risk_code
- 26/27/28-33-50/53
- hazard_code
- T+,N
- safety_code
- 13-28-36-45-60-61
- hazard_class
- 6.1
- packing_group
- II
- Hazard Classifications
- Acute Tox. 1 DermalAcute Tox. 2 InhalationAcute Tox. 2 OralAquatic Acute 1Aquatic Chronic 1STOT RE 2
- ストレージクラス
- 6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials
化学と産業
用途と製造
General Manufacturing InformationMercury, diphenyl-: INACTIVE
調製方法
純化方法Sublime it, then crystallise it from nitromethane or ethanol. If phenylmercuric halides are present, they can be converted to phenylmercuric hydroxide which, being much more soluble, remain in the alcohol or *benzene used for crystallisation. Thus, crude material (10g) is dissolved in warm ethanol (ca 150mL) and shaken with moist Ag2O (ca 10g) for 30minutes, then heated under reflux for 30minutes and filtered hot. Concentrating the filtrate by evaporation gives diphenylmercury, which is then recrystallised from *benzene [Blair et al. J Chem Soc 3174 1959]. [Beilstein 16 IV 1702.] TOXIC.
上流・下流製品情報
下流製品
サプライヤー11 社
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
阿法埃莎（中国）化学有限公司400-6106006 · [email protected]
梯希爱（上海）化工贸易有限公司021-61109150 · [email protected]
南通合润生物科技有限公司18362409333 · [email protected]
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司021-61415566 800-8193336 · [email protected]
天津荣燊化工有限公司18317763565; 18317763565 · [email protected]
陕西缔都医药化工有限公司+86-29-81139210 +86-17392587031 · [email protected]
厦门盈融达化工有限公司+86-0592-6210733 · [email protected]
深圳聚合生化科技有限公司+86-400-002-6226 13028896684 · [email protected]
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.+8618950047208 · [email protected]
陕西缔都化学有限公司17691182729 17392216275 · [email protected]
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