CAS 13735-81-4 Benzene, [1-[(trimethylsilyl)oxy]ethenyl]- (HCID 117406)

名称と識別子

優先名称: Benzene, [1-[(trimethylsilyl)oxy]ethenyl]-
IUPAC: trimethyl(1-phenylethenoxy)silane
現地名: 1-フェニル-1-トリメチルシリルオキシエチレン
英語名: 1-Phenyl-1-trimethylsiloxyethylene
分子式: C11H16OSi
分子量: 192.33

名称と別名

Trimethyl((1-phenylvinyl)oxy)silaneTrimethyl[(1-phenylvinyl)oxy]silaneEINECS 237-308-11-Phenyl-1-(trimethylsiloxy)ethylenealpha-(Trimethylsiloxy)styreneBenzene, (1-((trimethylsilyl)oxy)ethenyl)-Silane, trimethyl((1-phenylethenyl)oxy)-Silane, trimethyl[(1-phenylethenyl)oxy]-DTXSID10884636Benzene, [1-[(trimethylsilyl)oxy]ethenyl]-RefChem:562065DTXCID101024066

名称をさらに表示

1-フェニル-1-トリメチルシリルオキシエチレン(トリメチルシリル)(1-フェニルビニル)エーテル[1-(トリメチルシリルオキシ)ビニル]ベンゼン(1-フェニルビニルオキシ)トリメチルシラントリメチル[(1-フェニルエテニル)オキシ]シラン1-(トリメチルシロキシ)ビニルベンゼン[(1-フェニルエテニル)オキシ]トリメチルシラン[1-(トリメチルシロキシ)エテニル]ベンゼントリメチル[(1-フェニルビニル)オキシ]シランα-トリメチルシロキシスチレントリメチルシリル(1-フェニルエテニル)エーテル[[1-(フェニル)ビニル]オキシ]トリメチルシラン1-フェニル-1-トリメチルシロキシエテン1-フェニル-1-(トリメチルシリルオキシ)エテン[1-(トリメチルシロキシ)ビニル]ベンゼン(α-メチレンベンジルオキシ)トリメチルシラン1-トリメチルシリルオキシ-1-フェニルエテン[1-[(トリメチルシリル)オキシ]ビニル]ベンゼン(1-フェニルエテニル)(トリメチルシリル)エーテル1-[(トリメチルシリル)オキシ]-1-フェニルエテンDK071DKFELEX0126α-(trimethylsiloxy)styreneà-(trimethylsiloxy)styreneα-(Trimethylsilyloxy)styrene1-Phenyl-1-trimethylsiloxyetheneALPHA-(TRIMETHYLSILYLOXY)STYRENE(1-phenylvinyl)oxyTrimethylsilane

237-308-113735-81-41-Phenyl-1-trimethylsiloxyethylenetrimethyl(1-phenylethenoxy)silane1-Phenyl-1-trimethylsilyloxyethyleneC11H16OSiMFCD000085821-Phenyl-1-(trimethylsilyloxy)ethylene

データベース識別子

CAS: 13735-81-4
PubChem CID: 117406
DTXSID: DTXSID10884636
UNII: X26FF7XFN5
EC Number: 237-308-1
Nikkaji: J236.395J

物性

構造計算による物性

極性表面積: 9.2 Å²
水素結合供与体数: 0
水素結合受容体数: 1
回転可能結合数: 3
重原子数: 13
形式電荷: 0
複雑度: 175

物理化学的性質

融点: 122 · 122-123 °C
沸点: 88 · 88-89 °C/11 mmHg (lit.)
比重(密度): 0.938 g/mL · 0.938 g/mL at 25 °C (lit.)
蒸気密度: 1 · >1 (vs air)
屈折率: 20 · n20/D 1.502(lit.)
闪点: 174 °F · 174 °F
貯蔵温度: 2 · 2-8°C
外見: clear liquid
色: Colorless to Light orange to Yellow
比重: 0.938 · 0.938
水溶解度: 水と反応する。
BRN: 1306914 · 1306914
InChI: 1S/C11H16OSi/c1-10(12-13(2,3)4)11-8-6-5-7-9-11/h5-9H,1H2,2-4H3
InChIKey: AFFPCIMDERUIST-UHFFFAOYSA-N
SMILES: C[Si](C)(C)OC(=C)c1ccccc1
CAS データベース: 13735 · 13735-81-4(CAS DataBase Reference)
EPAの化学物質情報: Silane, trimethyl[(1-phenylethenyl)oxy]- (13735-81-4)

安全と法規制

GHS分類

GHS Classification · 5 件

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (97.5%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Hazard Classes and CategoriesSkin Irrit. 2 (100%)；Eye Irrit. 2 (100%)；STOT SE 3 (97.5%)

安全データ

F: 10-21
wgk: 3
tsca: TSCA listed
hs_code: 2931900090
risk_code: 36/37/38
消防法: 危-4-3-III
hazard_code: Xi
safety_code: 26-36
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3
ストレージクラス: 10 - Combustible liquids

化学と産業

用途と製造

General Manufacturing InformationBenzene, [1-[(trimethylsilyl)oxy]ethenyl]-: ACTIVE

応用分野 · 2 件

使用1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of β-amino ketones in water via Mannich-type reaction and cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction. It is also used as chemical additives and intermediates.

一般的な説明1-Phenyl-1-trimethylsiloxyethylene is a styrene type silyl enol ether, reacts with formaldehyde and 2,4-pentanedione to yield the corresponding dihydropyran. It also undergoes Mukaiyama aldol reaction with aldehydes in water in the presence of amphiphilic calix[6]arene derivatives as surfactants.