1,4-ビス[(t-ブチルパーオキシ)イソプロピル]ベンゼン

Bis(tert-butyldioxyisopropyl)benzene

HCID 11856263

基本情報

CAS
25155-25-3
標準SMILES
CC(C)(C)OOC(C)(C)c1ccccc1C(C)(C)OOC(C)(C)C
InChIKey
CCNDOQHYOIISTA-UHFFFAOYSA-N
分子式
C20H34O4
平均分子量
338.5 g/mol
単同位体質量
338.24570956

概要

Bis(tert-butyldioxyisopropyl)benzene is a white crystalline solid. (NTP, 1992)

名称と識別子

優先名称
Bis(tert-butyldioxyisopropyl)benzene
IUPAC
1,2-bis(2-tert-butylperoxypropan-2-yl)benzene
現地名
1,4-ビス[(t-ブチルパーオキシ)イソプロピル]ベンゼン
英語名
Bis(tert-butyldioxyisopropyl)benzene
分子式
C20H34O4
分子量
338.48

名称と別名

Bis(tert-butyldioxyisopropyl)benzeneLuperox 802Peroxide, (phenylenediisopropylidene)bis(tert-butylBIS(ALPHA-(TERT-BUTYLPEROXY)ISOPROPYL)BENZENEBIS[ALPHA-(TERT-BUTYLPEROXY)ISOPROPYL]BENZENEBIS(1-(TERT-BUTYLDIOXY)-1-METHYLETHYL)BENZENEBIS[1-(TERT-BUTYLDIOXY)-1-METHYLETHYL]BENZENEPEROXIDE, (PHENYLENEDIISOPROPYLIDENE)BIS[TERT-BUTYLPEROXIDE,(PHENYLENEBIS(1-METHYLETHYLIDENE)BIS(1,1-DIMETHYLETHYL)),PEROXIDE,[PHENYLENEBIS(1-METHYLETHYLIDENE)BIS(1,1-DIMETHYLETHYL)],Vul-CupVul-Cup R
名称をさらに表示
α,α'-ビス(2-tert-ブチルペルオキシイソプロピル)ベンゼンビス(1-tert-ブチルペルオキシ-1-メチルエチル)ベンゼン1,4(または1,3)ビス[(tブチルパ-オキシ)イソプロピル]ベンゼン1,4-ビス[(t-ブチルパーオキシ)イソプロピル]ベンゼンビス(1tブチルペルオキシ1メチルエチル)ベンゼンBIS(TERT-BUTYLPEROXYISOPROPYL)BENZENEdi-(2-tert-butylperoxyisopropyl)benzeneBis(t-butylperoxy isopropyl)benzene (BIPB)- BIPBvul-cuprVAROX VC-RLuperox? FLuperox(R)Perkadox 14
PBMBDPPERBUTYL PTPEROXIMON FVul-Cup 40KEPERKADOX 14SFIPERKADOX 14SPERKADOX 14S-FLRefChem:569280

データベース識別子

CAS
25155-25-3
PubChem CID
11856263
Nikkaji
J155.570G

物性

構造計算による物性

XLogP
4.5
極性表面積
36.9 Ų
水素結合供与体数
0
水素結合受容体数
4
回転可能結合数
8
重原子数
24

実験および物理化学的性質

Solubilityless than 1 mg/mL at 70 °F (NTP, 1992)
Physical DescriptionBis(tert-butyldioxyisopropyl)benzene is a white crystalline solid. (NTP, 1992)

物理化学的性質

融点
44 · 44-48 °C(lit.)
沸点
434.61 °C · 434.61°C (rough estimate)
比重(密度)
1.63 g/mL · 1.63 g/mL at 25 °C(lit.)
蒸気圧
0 Pa · 0Pa at 20℃
屈折率
1.6 · 1.6000 (estimate)
闪点
230 °F · >230 °F

安全と法規制

危険有害性情報

DOT LabelOrganic Peroxide
Fire HazardsFlash point data for this compound are not available, however, it is probably combustible. (NTP, 1992)
Health HazardsExcerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:
Reactive GroupPeroxides, Organic
Reactivity AlertsExplosive
Reactivity ProfileBIS(TERT-BUTYLDIOXYISOPROPYL)BENZENE may polymerize and/or decompose if heated. (NTP, 1992)

安全と保護具

Fire FightingFires involving this compound can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1 件

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1 件

SMALL SPILLS AND LEAKAGE: Should a spill occur while you are handling this chemical, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with 60-70% ethanol and transfer the dampened material to a suitable container. Use absorbent paper dampened with 60-70% ethanol to pick up any remaining material. Seal the absorbent paper, and any of your clothes, which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:
Personal Protective Equipment (PPE) · 1 件

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

安全データ

wgk
1
tsca
TSCA listed
rtecs
SD8431900
ridadr
UN 3106 5.2
毒性
skn-rbt 100%/24H MLD HERBU* PRC-304
risk_code
8-36/37-20-7-53

化学と産業

応用分野

一般的な説明White crystalline solid.

サプライヤー55 社

Shandong chuangyingchemical Co., Ltd.18853181302 · [email protected]
Hebei Chuanghai Biotechnology Co., Ltd+86-17732866630 · [email protected]
杭州品高化工有限公司0571-87658025 · [email protected]
陕西缔都新材料有限公司029-63373950 17392216152 · [email protected]
湖南嘉航医药科技有限公司85521272 15200744171 · [email protected]

関連反応

1 件

化合物ノート

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