Benzyl iodide (HCID 12098)

概要

Low-melting crystals or a colorless liquid. Melting point 34.1 °C. Insoluble in water and denser (1.74 g / cm3) than water. Hence sinks in water. Toxic by ingestion, inhalation and skin absorption. Very irritating to skin and eyes.

名称と識別子

優先名称: Benzyl iodide
IUPAC: iodomethylbenzene
現地名: α-ヨードトルエン
英語名: BENZYL IODIDE
分子式: C7H7I
分子量: 218.04

名称と別名

(Iodomethyl)benzeneBENZYL IODIDEiodomethylbenzeneBenzene, (iodomethyl)-alpha-IodotolueneFraissiteEINECS 210-623-1UN2653.alpha.-Iodotoluene859JV557EVDTXSID6060715UN 2653

名称をさらに表示

ω-ヨードトルエンα-ヨードトルエンヨードメチルベンゼンヨードフェニルメタンよう化ベンジル(ヨードメチル)ベンゼンベンジルヨージドヨウ化ベンジルヨウ化物SKL717Iodotoluolα-Iodotoluene?-iodotoluenebenzene,iodomethyl-

alphaIodotoluenebenzene, (iodomethyl)RefChem:118874DTXCID1043201InChI=1/C7H7I/c8-6-7-4-2-1-3-5-7/h1-5H,6HXJTQJERLRPWUGL-UHFFFAOYSA-N620-05-3Iodophenylmethane

データベース識別子

CAS: 620-05-3
PubChem CID: 12098
DTXSID: DTXSID6060715
UNII: 859JV557EV
EC Number: 210-623-1
Nikkaji: J7.045I

物性

構造計算による物性

XLogP: 3.4
極性表面積: 0 Å²
水素結合供与体数: 0
水素結合受容体数: 0
回転可能結合数: 1
重原子数: 8
形式電荷: 0
複雑度: 55.4

実験および物理化学的性質

Chemical ClassesOther Classes -> Halogenated Monoaromatics

SpringerMaterials PropertiesBoiling point

Physical Description · 2 件

Low-melting crystals or a colorless liquid. Melting point 34.1 °C. Insoluble in water and denser (1.74 g / cm3) than water. Hence sinks in water. Toxic by ingestion, inhalation and skin absorption. Very irritating to skin and eyes.

Low-melting solid or colorless liquid; [CAMEO]

物理化学的性質

融点: 280 · 280-282℃
沸点: 218 ℃ · 218℃
比重(密度): 1.75 · 1.750
屈折率: 1.633 · 1.6330
闪点: 98 ℃ · 98℃
貯蔵温度: 2 · under inert gas (nitrogen or Argon) at 2–8 °C
Dielectric constant: 6.1 · 6.1(20℃)
InChI: InChI=1S/C7H7I/c8-6-7-4-2-1-3-5-7/h1-5H,6H2
InChIKey: XJTQJERLRPWUGL-UHFFFAOYSA-N
SMILES: C1(CI)=CC=CC=C1
CAS データベース: 620 · 620-05-3
EPAの化学物質情報: Benzene, (iodomethyl)- (620-05-3)

化学的性質

化学的特性Colorless crystals or liquid. Soluble in alcohol, carbon disulfide, ether; insoluble in water.

安全と法規制

GHS分類

GHS Classification · 4 件

Warning

H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

The GHS information provided by 1 company from 1 notification to the ECHA C&L Inventory.

危険有害性情報

Regulatory InformationThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelPoison

Fire Hazards · 2 件

Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:

· Combustible material: may burn but does not ignite readily.

Health Hazards · 2 件

Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:

· TOXIC and/or CORROSIVE; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death.

Hazards SummaryA strong skin and eye irritant; Toxic by ingestion, inhalation and skin absorption; [CAMEO]

DOT ID and Guide2653 156

安全と保護具

Fire FightingExcerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:

Accidental Release Measures · 2 件

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2 件

Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).

Nonfire Spill ResponseExcerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:

Isolation and Evacuation · 2 件

Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:

Immediate precautionary measure

安全データ

tsca: TSCA listed
ridadr: UN 2653
hs_code: 29039990
hazard_class: 6.1
packing_group: II

化学と産業

用途と製造

General Manufacturing InformationBenzene, (iodomethyl)-: ACTIVE

応用分野

使用A tear gas.

一般的な説明Low-melting crystals or a colorless liquid. Melting point 34.1°C. Insoluble in water and denser (1.74 g / cm3) than water. Hence sinks in water. Toxic by ingestion, inhalation and skin absorption. Very irritating to skin and eyes.