m-エトキシアニリン

3-Ethoxyaniline

HCID 12120CAS 621-33-0

基本情報

標準SMILES
CCOc1cccc(N)c1
InChIKey
WEZAHYDFZNTGKE-UHFFFAOYSA-N
分子式
C8H11NO
平均分子量
137.18 g/mol
単同位体質量
137.08406397

概要

M-phenetidine is a dark red liquid. (NTP, 1992)

名称と識別子

優先名称
3-Ethoxyaniline
IUPAC
3-ethoxyaniline
現地名
m-エトキシアニリン
英語名
3-Ethoxyaniline
分子式
C8H11NO
分子量
137.18

名称と別名

3-ETHOXYANILINEm-Phenetidine621-33-03-EthoxybenzenamineBenzenamine, 3-ethoxy-m-Ethoxyaniline(3-ethoxyphenyl)amineCCRIS 4696DTXSID00258623-PhenetidineNSC 9817EINECS 210-680-2
名称をさらに表示
3-エトキシアニリンm-フェネチジンm-エトキシアニリンメタフェネチジン3-アミノフェネトール(m-フェネチジン)M‐フェネチジンAKOS BBB/405N-phenetidineMETA-PHENETIDINE3'-AMINOPHENETOLm-Aminophenetole
XE9KKL972RBRN 0971028AI3-15397PHENETIDINE, M-NSC-9817M-ETHOXYPHENYLAMINEDTXCID7058623-AMINOPHENYL ETHYL ETHER

データベース識別子

CAS
621-33-0
PubChem CID
12120
DTXSID
DTXSID0025862
ChEMBL
CHEMBL1466168
UNII
XE9KKL972R
EC Number
210-680-2
Nikkaji
J101.236C

物性

構造計算による物性

XLogP
1.3
極性表面積
35.3 Ų
水素結合供与体数
1
水素結合受容体数
2
回転可能結合数
2
重原子数
10

実験および物理化学的性質

Chemical ClassesNitrogen Compounds -> Amines, Aromatic
SpringerMaterials PropertiesDiamagnetic susceptibility
Density1.032 (NTP, 1992) - Denser than water; will sink
Solubility1 to 5 mg/mL at 68 °F (NTP, 1992)
Flash Pointgreater than 235 °F (NTP, 1992)
Boiling Point478 °F at 760 mmHg (NTP, 1992)

物理化学的性質

融点
204 °C · 204 °C
沸点
248 °C · 248 °C(lit.)
比重(密度)
1.032 g/mL · 1.032 g/mL at 25 °C(lit.)
屈折率
20 · n20/D 1.566(lit.)
闪点
230 °F · >230 °F
貯蔵温度
30 °C · Store below +30°C.

化学的性質

化学的特性light yellow to dark red liquid

安全と法規制

GHS分類

GHS Classification · 5 件

This chemical does not meet GHS hazard criteria for 48.7% (37 of 76) of reports.

Danger

H301 (51.3%): Toxic if swallowed [Danger Acute toxicity, oral]

P260, P261, P262, P264, P270, P271, P280, P301+P316, P302+P352, P304+P340, P316, P319, P321, P330, P361+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 76 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory Information3-Phenetidine: Does not have an individual approval but may be used under an appropriate group standard
DOT LabelPoison
Fire HazardsThis chemical is probably combustible. (NTP, 1992)
Health HazardsSYMPTOMS: Symptoms of exposure to this compound may include cyanosis, hypothermia, headache, drowsiness, vomiting, nephritis and irritation of the alimentary tract.
Hazards SummaryMay cause cyanosis, hypothermia, drowsiness, and nephritis; [NTP] May cause irritation; May induce methemoglobinemia; Toxic by ingestion, inhalation, and skin absorption; [Sigma-Aldrich MSDS] See p-Phenetidine.
Reactive GroupAmines, Aromatic

安全と保護具

Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1 件

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1 件

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:
Personal Protective Equipment (PPE) · 1 件

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

毒性情報

Adverse EffectsMethemoglobinemia - The presence of increased methemoglobin in the blood; the compound is classified as secondary toxic effect

安全データ

F
8-10-23
wgk
3
tsca
TSCA listed
rtecs
SI5400000
ridadr
UN 2311 6.1/PG 3
毒性
mma-sat 1 mg/plate EMMUEG 11(Suppl12),1,88

化学と産業

用途と製造

General Manufacturing InformationBenzenamine, 3-ethoxy-: INACTIVE

応用分野

使用3-Ethoxyaniline was used as starting reagent in the synthesis of 1,2,3,4-tetrahydroacridinylhydrazides.

一般的な説明Dark red liquid.

サプライヤー50 社

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
南京凯美西化工有限公司02558748998 18951874644 · [email protected]
Hebei Chuanghai Biotechnology Co., Ltd+86-17732866630 · [email protected]
上海策嵘生物科技有限公司[email protected]
温州共赢化学有限公司+86-0086-577-64498589 +86-15355981851 · [email protected]

関連反応

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