素酸（６水）
Cupric perchlorate hexahydrate
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基本情報
- CAS
10294-46-9- 標準SMILES
O.O.O.O.O.O.[Cu+2].[O-][Cl+3]([O-])([O-])[O-].[O-][Cl+3]([O-])([O-])[O-]- InChIKey
NHELIHXBJRANPL-UHFFFAOYSA-L- 分子式
- Cl2CuH12O14
- 平均分子量
- 370.54 g/mol
- 単同位体質量
- 368.890008
名称と識別子
- 優先名称
- Cupric perchlorate hexahydrate
- IUPAC
- copper;diperchlorate;hexahydrate
- 現地名
- 素酸（６水）
- 英語名
- COPPER(II) PERCHLORATE HEXAHYDRATE
- 分子式
- ClCuH3O5
- 分子量
- 182.02
名称と別名
10294-46-9Cupric perchlorate hexahydrateCopper diperchlorate hexahydrateCupric diperchlorate hexahydrateCopper(2+) perchlorate hexahydrate57JSH2LO1GCopper perchlorate (Cu(ClO4)2) hexahydratePerchloric acid, copper(2+) salt, hexahydrateDTXSID00145581RefChem:128834DTXCID0068072677-711-3
名称をさらに表示
素酸（６水）過塩素酸銅（６水塩）過塩素酸銅(II)六水和物(過塩素酸第二銅六水和物)過塩素酸銅(Ⅱ)六水和物過塩素酸銅(II) 六水和物過塩素酸銅(II)六水和物, 98+%過塩素酸銅(II)六水和物, 99.999% (metals basis)過塩素酸銅(II)六水和物, Reagent Grade二過塩素酸銅(II)・6水和物Cu(ClO?)?.6H?OCOPPER (II) PERCHLORATEcopperperchlorate hydrateCUPRIC PERCHLORATE, HYDRATEDCopper(II)perchlorate hydrateCOPPER(+2)PERCHLORATE HEXAHYDRATECopper(Ⅱ) perchlorate hexahydrate
Copper(II) perchlorate hexahydratecopper;diperchlorate;hexahydrateUNII-57JSH2LO1GCupric perchlorate hexahydrate [MI]MFCD00149666Cl2CuH12O14Copper perchlorate hexahydrateCopper(II) perchlorate hydrate
データベース識別子
- CAS
10294-46-9- PubChem CID
- 12846356
- DTXSID
DTXSID00145581- UNII
- 57JSH2LO1G
- EC Number
- 677-711-3
物性
構造計算による物性補完中
- 極性表面積
- 155 Ų
- 水素結合供与体数
- 6
- 水素結合受容体数
- 14
- 回転可能結合数
- 0
- 重原子数
- 17
- 形式電荷
- 0
- 複雑度
- 95.8
実験および物理化学的性質
Chemical ClassesMetals -> Metals, Inorganic Compounds
Physical DescriptionDeep blue solid; [Merck Index] Blue odorless crystals; Hygroscopic; [Alfa Aesar MSDS]
物理化学的性質
- 融点
- 82 °C · 82°C
- 沸点
- 120 °C · 120°C
- 比重(密度)
- 2.225 g/mL · 2.225 g/mL at 25 °C(lit.)
- 屈折率
- 1.505 · 1.505
- 溶解性
- 2 OAc, · very soluble in ethanol, H2OAc, acetone; slightly soluble in ethyl ether
- 外見
- 結晶の付着
- 色
- 青い
- 比重
- 2.23 · 2.23
- 水溶解度
- 水、メタノール、エタノール、酢酸、無水酢酸、アセトンに可溶
- Merck
- 14 · 14,2647
- 安定性
- 吸湿性
- InChI
- 1S/2ClHO4.Cu.6H2O/c2*2-1(3,4)5;;;;;;;/h2*(H,2,3,4,5);;6*1H2/q;;+2;;;;;;/p-2
- InChIKey
- NHELIHXBJRANPL-UHFFFAOYSA-L
- SMILES
- O.O.O.O.O.O.[Cu++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
- CAS データベース
安全と法規制
安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。
GHS分類
GHS Classification
Danger
H272 (100%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]
P210, P220, P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 44 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
危険有害性情報
Regulatory Information
Chemical: Perchloric acid, copper(2+) salt, hexahydrate
Copper perchlorate hexahydrate: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
Hazards SummaryAn oxidizer that may cause fire on contact with combustible materials; A skin and strong eye irritant; [Alfa Aesar MSDS] See Cupric perchlorate. See PERCHLORATES.
Hazard Classes and CategoriesOx. Sol. 2 (100%)
安全と保護具
Exposure Control and Personal Protection0.01 [mg/m3], respirable fraction (Cu, inorganic cmpnds)[German Research Foundation (DFG)]
Threshold Limit Values (TLV)1.0 [mg/m3], as Cu
Permissible Exposure Limit (PEL)1.0 [mg/m3], as Cu
Immediately Dangerous to Life or Health (IDLH)
化学と産業
用途と製造
Uses
Used as an analytical reagent, in copper electrodeposition, and in combustion catalysts; [Merck Index]
Electroplating [Category: Plate]
応用分野
使用Copper(II) perchlorate hexahydrate is a strong oxidizing agent.
一般的な説明The monoclinic structure of copper perchlorate hexahydrate was analyzed by X-ray diffraction. The product may be used as a catalyst during the reaction of 5-methylisophthalaldehyde with 1,3-diaminopropane. Benzaldehyde semicarbazones, reacted with copper perchlorate hexahydrate in acetonitrile, may yield corresponding 1,2,4-triazolin-5-ones.
調製方法
純化方法Crystallise it from distilled water. The anhydrous salt is hygroscopic.
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