テトラフルオロほう酸(-)-1,2-ビス((2S,5S)-2,5-ジメチルホスホラノ)エタン(シクロオクタジエン)ロジウム(I) [(S,S)-ME-BPE-RH]

1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborate

HCID 12964417

ノート反応

部分構造検索類似構造を探す

基本情報

CAS: 213343-65-8
標準SMILES: C1=C\CC/C=C\CC/1.C[C@H]1CC[C@H](C)P1CCP1[C@@H](C)CC[C@@H]1C.F[B-](F)(F)F.[Rh]
InChIKey: LKVIVYCYPYTYSO-ASDDUFFSSA-N
分子式: C22H40BF4P2Rh-
平均分子量: 556.2 g/mol
単同位体質量: 556.1694954

名称と識別子

優先名称: 1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborate
IUPAC: (1Z,5Z)-cycloocta-1,5-diene;(2S,5S)-1-[2-[(2S,5S)-2,5-dimethylphospholan-1-yl]ethyl]-2,5-dimethylphospholane;rhodium;tetrafluoroborate
現地名: テトラフルオロほう酸(-)-1,2-ビス((2S,5S)-2,5-ジメチルホスホラノ)エタン(シクロオクタジエン)ロジウム(I) [(S,S)-ME-BPE-RH]
英語名: (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium (I) tetrafluoroborate
分子式: C22H40BF4P2Rh-
分子量: 556.21

名称と別名

213343-65-81,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborateMFCD32853739(1Z,5Z)-cycloocta-1,5-diene;(2S,5S)-1-[2-[(2S,5S)-2,5-dimethylphospholan-1-yl]ethyl]-2,5-dimethylphospholane;rhodium;tetrafluoroborateC22H40BF4P2Rh-MFCD04038742DTXSID60514133(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I) tetrafluoroborateSY068615F556560(-)-1,2-bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)-rhodium (I) tetrafluoroborate(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)-rhodium(I) tetrafluoroborate

名称をさらに表示

テトラフルオロほう酸(-)-1,2-ビス((2S,5S)-2,5-ジメチルホスホラノ)エタン(シクロオクタジエン)ロジウム(I) [(S,S)-ME-BPE-RH](S,S)-ME-BPE-RH[((SS)-Me-BPE)Rh(COD)]BF41,2-Bis((2S,5S)-2,5-dimethyL(à)-Methyl 2-benzyloxycarbonylamino-2-(dimethoxyphosphinyl)acetat(2S,5S)-1-[2-[(2S,5S)-2,5-dimethylphospholan-1-yl]ethyl]-2,5-dimethylphospholane(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium (I) tetrafluoroborate(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium (I) tetrafluoroborate(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate(+)-1,2-Bis[(2S,5S)-2,5-diMethylphospholano]ethane(1,5-cyclooctadiene)rhodiuM(I)tetrafluoroborate,97%

(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)-rhodium(I)tetrafluoroborate(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE(1Z,5Z)-cycloocta-1,5-diene;(2S,5S)-1-[2-[(2S,5S)-2,5-dimethylphospholan-1-yl]ethyl]-2,5-dimethyl-phospholane;rhodium;tetrafluoroborate1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate

データベース識別子

CAS: 213343-65-8
PubChem CID: 12964417
DTXSID: DTXSID60514133
EC Number: 633-653-0

物性

構造計算による物性

極性表面積: 0 Å²
水素結合供与体数: 0
水素結合受容体数: 5
回転可能結合数: 3
重原子数: 30
形式電荷: -1
複雑度: 277

物理化学的性質

融点: 152.2 · 152.2-156.3 °C
貯蔵温度: 2 · 2-8°C, protect from light, stored under nitrogen
外見: 結晶性粉末
色: オレンジ→赤→茶色
InChIKey: CVUPEPGZCZHSOF-ASDDUFFSSA-N
SMILES: [Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C[C@H]2CC[C@H](C)P2CCP3[C@@H](C)CC[C@@H]3C

安全と法規制

GHS分類

GHS Classification · 4 件

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 41 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.