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Cupric lactate

HCID 13145
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
部分構造検索類似構造を探す

基本情報

CAS
16039-52-4
標準SMILES
CC(O)C(=O)[O-].CC(O)C(=O)[O-].[Cu+2]
InChIKey
DYROSKSLMAPFBZ-UHFFFAOYSA-L
分子式
C6H10CuO6
平均分子量
241.69 g/mol
単同位体質量
240.977335

概要

Greenish-blue crystals or granular powder.

名称と識別子

優先名称
Cupric lactate
IUPAC
copper bis(2-hydroxypropanoate)

名称と別名

CUPRIC LACTATE16039-52-4Copper lactateCopper, bis(lactato)-814-81-3Caswell No. 243HSDB 263UNII-4P8B1X24UA4P8B1X24UACopper, bis(2-hydroxypropanoato-O1,O2)-EINECS 240-177-3EPA Pesticide Chemical Code 023302
名称をさらに表示
NSC 112239CUPRIC LACTATE [HSDB]Bis(2-(hydroxy-kappaO)propanoato-kappaO)copperDTXSID40894965NSC-112239Copper, bis(2-(hydroxy-kappaO)propanoato-kappaO)-Propanoic acid, 2-hydroxy-, copper(2+) salt (2:1)COPPER, BIS(2-(HYDROXY-.KAPPA.O)PROPANOATO-.KAPPA.O)-

データベース識別子

CAS
16039-52-4、814-81-3
PubChem CID
13145
DTXSID
DTXSID40894965
UNII
4P8B1X24UA
EC Number
240-177-3
Nikkaji
J2.745.408I

物性

構造計算による物性

極性表面積
121 Ų
水素結合供与体数
2
水素結合受容体数
6
回転可能結合数
0
重原子数
13
形式電荷
0
複雑度
53.5

実験および物理化学的性質

Chemical ClassesMetals -> Metals, Inorganic Compounds
Color/FormGreenish-blue crystals or granular powder
Solubility · 3 件

GREEN TO BLUE CRYSTALS. READILY SOL IN WATER; PRACTICALLY INSOL IN ALCOHOL /DIHYDRATE/

DARK BLUE, MONOCLINIC; SOL IN AMMONIUM HYDROXIDE /DIHYDRATE/

Soluble in water and ammonium hydroxide

Physical Description · 2 件

Greenish-blue crystals or granular powder.

Greenish-blue solid; [HSDB]

安全と法規制

安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 4 件

Warning

H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]

P264, P270, P301+P317, P330, and P501 (click each P-code to see the statement)

The GHS information provided by 1 company from 1 notification to the ECHA C&L Inventory.

危険有害性情報

Health HazardsSOLID: Harmful if swallowed. Irritating to skin and eyes. (USCG, 1999)
Hazards SummarySee Copper.
Reactive GroupAlcohols and Polyols
OSHA StandardsPermissible Exposure Limit: Table Z-1 8-hr Time Weighted Avg: 1 mg/cu m. /Copper dusts and mists (as Cu)/
Reactivity Profile · 1 件

Salts, basic, such as COPPER LACTATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydroxide ions and have pH's greater than 7.0. They react as bases to neutralize acids. These neutralizations generate heat, but less or far less than is generated by neutralization of the bases in reactivity group 10 (Bases) and the neutralization of amines. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible.

Air and Water ReactionsWater soluble.
NIOSH RecommendationsRecommended Exposure Limit: 10 Hr Time-Weighted Avg: 1 mg/cu m. /Copper (dusts and mists)/
Clean Water Act RequirementsToxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluent limitations. /Copper and cmpd/

化学と産業

薬理情報

Metabolism/Metabolites · 1 件

Copper is mainly absorbed through the gastrointestinal tract, but it can also be inhalated and absorbed dermally. It passes through the basolateral membrane, possibly via regulatory copper transporters, and is transported to the liver and kidney bound to serum albumin. The liver is the critical organ for copper homoeostasis. In the liver and other tissues, copper is stored bound to metallothionein, amino acids, and in association with copper-dependent enzymes, then partitioned for excretion through the bile or incorporation into intra- and extracellular proteins. The transport of copper to the peripheral tissues is accomplished through the plasma attached to serum albumin, ceruloplasmin or low-molecular-weight complexes. Copper may induce the production of metallothionein and ceruloplasmin. The membrane-bound copper transporting adenosine triphosphatase (Cu-ATPase) transports copper ions into and out of cells. Physiologically normal levels of copper in the body are held constant by alterations in the rate and amount of copper absorption, compartmental distribution, and excretion. (L277, L279)

用途と製造

Uses · 3 件

Used in copper-plating and fungicides; [HSDB]

Electroplating [Category: Plate]

Source of copper in copper-plating; fungicides /former/

関連反応

0 件
反応記録を作成

現在のフィルター条件では反応記録がありません。

化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
Hazard Classes and CategoriesAcute Tox. 4 (100%)
State Drinking Water Guidelines(AZ) ARIZONA 1300 ug/l /Copper/
Federal Drinking Water StandardsEPA 1300 ug/l (Action Level) /Copper/
Federal Drinking Water GuidelinesEPA 1000 ug/l /Copper/

安全と保護具

First AidCall a physician.
Exposure Control and Personal Protection0.01 [mg/m3], respirable fraction (Cu, inorganic cmpnds)[German Research Foundation (DFG)]
Nonfire Spill ResponseIsolate and remove discharged material. Notify local health and pollution control agencies. (USCG, 1999)
Disposal Methods · 1 件

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Minimum Risk LevelAcute Oral: 0.01 mg/kg/day (L134) Intermediate Oral: 0.01 mg/kg/day (L134)
Threshold Limit Values (TLV) · 3 件

1.0 [mg/m3], as Cu

8 hr Time Weighted Avg (TWA): 1 mg/cu m /Copper dusts and mists, as Cu/

Excursion Limit Recommendation: Excursions in worker exposure levels may exceed 3 times the TLV-TWA for no more than a total of 30 minutes during a work day, and under no circumstances should they exceed 5 times the TLV-TWA, provided that the TLV-TWA is not exceeded. /Copper dusts and mists, as Cu/

Permissible Exposure Limit (PEL)1.0 [mg/m3], as Cu
Immediately Dangerous to Life or Health (IDLH)100.0 [mg/m3], as Cu

毒性情報

Health Effects · 1 件

People must absorb small amounts of copper every day because copper is essential for good health, however, high levels of copper can be harmful. Very-high doses of copper can cause damage to your liver and kidneys, and can even cause death. Copper may induce allergic responses in sensitive individuals. (L278, L279)

Adverse EffectsOccupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.
Exposure RoutesOral (L277) ; inhalation (L277) ; dermal (L277)
Toxicity Summary · 1 件

Excess copper is sequestered within hepatocyte lysosomes, where it is complexed with metallothionein. Copper hepatotoxicity is believed to occur when the lysosomes become saturated and copper accumulates in the nucleus, causing nuclear damage. This damage is possibly a result of oxidative damage, including lipid peroxidation. Copper inhibits the sulfhydryl group enzymes such as glucose-6-phosphate 1-dehydrogenase, glutathione reductase, and paraoxonases, which protect the cell from free oxygen radicals. It also influences gene expression and is a co-factor for oxidative enzymes such as cytochrome C oxidase and lysyl oxidase. In addition, the oxidative stress induced by copper is thought to activate acid sphingomyelinase, which lead to the production of ceramide, an apoptotic signal, as well as cause hemolytic anemia. Copper-induced emesis results from stimulation of the vagus nerve. (L277, T49, A174, L280)

Signs and SymptomsBreathing high levels of copper can cause irritation of the nose and throat. Ingesting high levels of copper can cause nausea, vomiting, diarrhea, headache, dizziness, and respiratory difficulty. (L278, L279)
Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).

法規制情報

Clean Water Act RequirementsToxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluent limitations. /Copper and cmpd/
State Drinking Water Guidelines(AZ) ARIZONA 1300 ug/l /Copper/
Federal Drinking Water StandardsEPA 1300 ug/l (Action Level) /Copper/
Federal Drinking Water GuidelinesEPA 1000 ug/l /Copper/