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L-酒石酸銅(II)

Cupric tartrate

HCID 13155
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
部分構造検索類似構造を探す

基本情報

CAS
815-82-7
標準SMILES
O=C([O-])[C@H](O)[C@@H](O)C(=O)[O-].[Cu+2]
InChIKey
RSJOBNMOMQFPKQ-ZVGUSBNCSA-L
分子式
C4H4CuO6
平均分子量
211.62 g/mol
単同位体質量
210.930385

概要

Cupric tartrate appears as a green to blue odorless powder. Insoluble in water. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. It is noncombustible. Used for electroplating metals.

名称と識別子

優先名称
Cupric tartrate
IUPAC
copper (2R,3R)-2,3-dihydroxybutanedioate
現地名
L-酒石酸銅(II)
英語名
Cupric tartrate
分子式
C4H6CuO6
分子量
213.63

名称と別名

815-82-7CUPRIC TARTRATEcopper(II) tartrateUNII-GQ7IFQ18IRGQ7IFQ18IRHSDB 2692,3-Dihydroxybutanedioic acid copper saltEINECS 212-425-0NSC 112251CUPRIC TARTRATE [MI]CUPRIC TARTRATE [HSDB]DTXSID00883592
名称をさらに表示
(2R,3R)-2,3-ジヒドロキシこはく酸銅(II)酒石酸銅L-酒石酸銅(II)酒石酸銅(Ⅱ)二水和物銅(2+)=(2R,3R)-2,3-ジヒドロキシスクシナート酒石酸銅(II)三水和物(酒石酸第二銅三水和物)酒石酸銅(II)水和物(5R,6R)-5,6-ジヒドロキシ-1,3-ジオキサ-2-クプラシクロヘプタン-4,7-ジオンCOPPER(II) TARTRATE HYDRATENA-9111(±)-Tartaric acidKupfer(II)-tartratCUPRIC TARTRATE HYDRATECopper(II) (+)-L-tartrateCOPPER TARTRATE TRIHYDRATECUPRIC TARTRATE TRIHYDRATE
Tartaric acid, copper(2+) salt (1:1), (+)-NSC-112251(2R,3R)-2,3-Dihydroxybutanedioic acid copper (2+) salt (1:1)Butanedioic acid, 2,3-dihydroxy-, (R-(R*,R*))-, copper(2+) salt (1:1)BUTANEDIOIC ACID, 2,3-DIHYDROXY-(R-(R*,R*))-, COPPER(2+) SALT (1:1)BUTANEDIOIC ACID, 2,3-DIHYDROXY-[R-(R*,R*)]-, COPPER(2+) SALT (1:1)RefChem:128842DTXCID601023106

物性

構造計算による物性

極性表面積
121 Ų
水素結合供与体数
2
水素結合受容体数
6
回転可能結合数
1
重原子数
11
形式電荷
0
複雑度
123

実験および物理化学的性質

Chemical ClassesMetals -> Metals, Inorganic Compounds
Densitygreater than 1 (USCG, 1999)
Color/FormLIGHT BLUE POWDER
SolubilityGreen to blue, odorless powder; slightly sol in water; sol in acids, alkali solns. /Trihydrate/
Boiling PointTrihydrate decomposes on heating (USCG, 1999)
Physical Description · 2 件

Cupric tartrate appears as a green to blue odorless powder. Insoluble in water. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. It is noncombustible. Used for electroplating metals.

Light blue powder; [HSDB] Blue-green odorless crystalline powder; [MSDSonline]

物理化学的性質

融点
275 °C · ~275 °C (dec.)(lit.)
貯蔵温度
2 · under inert gas (nitrogen or Argon) at 2-8°C
溶解性
2 O; · slightly soluble in H2O; soluble in acid solutions, alkaline solutions
外見
結晶
色
緑から青
水溶解度
わずかに溶ける

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 4 件

Warning

H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]

P264, P270, P301+P317, P330, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 39 reports by companies from 1 notifications to the ECHA C&L Inventory.

危険有害性情報

Regulatory InformationThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
Health Hazards · 1 件

INHALATION: Inhalation of dust may cause nasal congestion. EYES: May cause conjunctivitis and edema of eyelids. SKIN: May irritate skin. INGESTION: Vomiting is caused by local irritant and astringent action of ionic copper on stomach and bowel. (USCG, 1999)

Hazards SummaryCan cause copper poisoning after ingestion; [HSDB] An irritant; May cause liver and kidney damage; [MSDSonline] See Copper.
Reactive GroupAlcohols and Polyols
OSHA StandardsPermissible Exposure Limit: Table Z-1 8-hr Time Weighted Avg: 1 mg/cu m. /Copper dusts and mists (as Cu)/
Reactivity Profile · 1 件

Acidic salts, such as CUPRIC TARTRATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.

化学と産業

用途と製造

Uses · 3 件

Used in baths for copper electroplating; [Merck Index]

Electroplating [Category: Plate]

In baths for copper electroplating

Methods of ManufacturingPrepd by reaction of K tartrate with Cu(NO3)2: Kirschner, Kiesling, J. Am. Chem. Soc. 82, 4174 (1960).
General Manufacturing InformationButanedioic acid, 2,3-dihydroxy- (2R,3R)-, copper(2+) salt (1:1): ACTIVE
応用分野 · 1 件

一般的な説明A green to blue odorless powder. Insoluble in water. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. Cupric tartrate is noncombustible. Used for electroplating metals.

サプライヤー53 社

北京华美互利生物化工010-56205725 · [email protected]
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江苏星科元信息科技有限公司400-605-7200 15335295587 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
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化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート

データベース識別子

CAS
815-82-7
PubChem CID
13155
DTXSID
DTXSID00883592
UNII
GQ7IFQ18IR
EC Number
212-425-0、605-641-5
Nikkaji
J7.114E
InChI
InChI=1/C4H6O6.Cu/c5-1(3(7)8)2(6)4(9)10;/h1-2,5-6H,(H,7,8)(H,9,10);/t1-,2-;/s3
InChIKey
XIPWCAOMSIUHSL-RZHFEHKBNA-N
SMILES
[C@H](O)(C(=O)O)[C@@H](O)C(=O)O.[Cu] |&1:0,5,r|
CAS データベース
815 · 815-82-7(CAS DataBase Reference)
EPAの化学物質情報
Cupric tartrate (815-82-7)

化学的性質

化学的特性bluish green crystal(s) [STR93]

Air and Water ReactionsInsoluble in water.
NIOSH RecommendationsRecommended Exposure Limit: 10 Hr Time-Weighted Avg: 1 mg/cu m. /Copper (dusts and mists)/
CERCLA Reportable Quantities · 1 件

Persons in charge of vessels or facilities are required to notify the National Response Center (NRC) immediately, when there is a release of this designated hazardous substance, in an amount equal to or greater than its reportable quantity of 100 lb or 45.4 kg. The toll free number of the NRC is (800) 424-8802; In the Washington D.C. metropolitan area (202) 426-2675. The rule for determining when notification is required is stated in 40 CFR 302.4 (section IV. D.3.b).

Clean Water Act Requirements · 2 件

Cupric tartrate is designated as a hazardous substance under section 311(b)(2)(A) of the Federal Water Pollution Control Act and further regulated by the Clean Water Act Amendments of 1977 and 1978. These regulations apply to discharges of this substance. This designation includes any isomers and hydrates, as well as any solutions and mixtures containing this substance.

Toxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluent limitations. /Copper and cmpd/

Hazard Classes and CategoriesAcute Tox. 4 (100%)
State Drinking Water Guidelines(AZ) ARIZONA 1300 ug/l /Copper/

安全と保護具

First AidCall a physician.
Exposure Control and Personal Protection0.1 [mg/m3], inhalable fraction (Cu, inorganic cmpnds)[German Research Foundation (DFG)]
Disposal Methods · 1 件

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Preventive Measures · 2 件

SRP: Local exhaust ventilation should be applied wherever there is an incidence of point source emissions or dispersion of regulated contaminants in the work area. Ventilation control of the contaminant as close to its point of generation is both the most economical and safest method to minimize personnel exposure to airborne contaminants.

SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.

Threshold Limit Values (TLV) · 3 件

1.0 [mg/m3], as Cu

8 hr Time Weighted Avg (TWA): 1 mg/cu m /Copper dusts and mists, as Cu/

Excursion Limit Recommendation: Excursions in worker exposure levels may exceed 3 times the TLV-TWA for no more than a total of 30 minutes during a work day, and under no circumstances should they exceed 5 times the TLV-TWA, provided that the TLV-TWA is not exceeded. /Copper dusts and mists, as Cu/

Permissible Exposure Limit (PEL)1.0 [mg/m3], as Cu
Immediately Dangerous to Life or Health (IDLH)100.0 [mg/m3], as Cu

毒性情報

Adverse EffectsOccupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.
Human Toxicity Excerpts · 2 件

SYMPTOMATOLOGY: PROMPT EMESIS (USUALLY WITHIN 5 TO 10 MIN /AFTER INGESTION/). ... BURNING PAIN IN MOUTH, ESOPHAGUS, & STOMACH. METALLIC TASTE IN MOUTH. DIARRHEA WITH OR WITHOUT COLICKY ABDOMINAL PAIN ... MELENA OR OCCULT BLOOD IN FECES. ... HEADACHE, COLD SWEAT, WEAK PULSE & OTHER SIGNS OF SHOCK ... .

JAUNDICE ... WHEN SEVERE, IT IS USUALLY DUE TO HEPATIC NECROSIS WITH SWOLLEN & PAINFUL LIVER. SOMETIMES LESION IS PROGRESSIVE. MILD JAUNDICE MAY EVIDENCE ACUTE HEMOLYTIC CRISIS WITHOUT LIVER INJURY.

Acceptable Daily IntakesAdjusted acceptable daily intake (AADI): 1.3 mg/l. /Copper/

法規制情報

CERCLA Reportable Quantities · 1 件

Persons in charge of vessels or facilities are required to notify the National Response Center (NRC) immediately, when there is a release of this designated hazardous substance, in an amount equal to or greater than its reportable quantity of 100 lb or 45.4 kg. The toll free number of the NRC is (800) 424-8802; In the Washington D.C. metropolitan area (202) 426-2675. The rule for determining when notification is required is stated in 40 CFR 302.4 (section IV. D.3.b).

Clean Water Act Requirements · 2 件

Cupric tartrate is designated as a hazardous substance under section 311(b)(2)(A) of the Federal Water Pollution Control Act and further regulated by the Clean Water Act Amendments of 1977 and 1978. These regulations apply to discharges of this substance. This designation includes any isomers and hydrates, as well as any solutions and mixtures containing this substance.

Toxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluent limitations. /Copper and cmpd/

State Drinking Water Guidelines(AZ) ARIZONA 1300 ug/l /Copper/
Federal Drinking Water StandardsEPA 1300 ug/l (Action Level) /Copper/
Federal Drinking Water GuidelinesEPA 1000 ug/l /Copper/

安全データ

wgk
3
tsca
TSCA listed
ridadr
UN 9111
安衛法
57,57-2
有毒物質データの
815-82-7(Hazardous Substances Data)
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