2-メチル-1-ニトロナフタレン

2-Methyl-1-nitronaphthalene

HCID 13432

基本情報

CAS
881-03-8
標準SMILES
Cc1ccc2ccccc2c1[N+](=O)[O-]
InChIKey
IZNWACYOILBFEG-UHFFFAOYSA-N
分子式
C11H9NO2
平均分子量
187.19 g/mol
単同位体質量
187.06332853

概要

1-nitro-2-methylnaphthalene is a yellow solid. (NTP, 1992)

名称と識別子

優先名称
2-Methyl-1-nitronaphthalene
IUPAC
2-methyl-1-nitronaphthalene
現地名
2-メチル-1-ニトロナフタレン
英語名
2-Methyl-1-nitronaphthalene
分子式
C11H9NO2
分子量
187.19

名称と別名

2-METHYL-1-NITRONAPHTHALENE1-Nitro-2-methylnaphthaleneNaphthalene, 2-methyl-1-nitro-CCRIS 4680DTXSID2025761NSC 7516EINECS 212-917-5UNII-0IG2R1R9F7BRN 19543100IG2R1R9F7NSC-7516DTXCID105761
名称をさらに表示
2-メチル-1-ニトロナフタレン1-ニトロ-2-メチルナフタレン2-METHYL-1-NITROPHTHALENE2-methyl-1-nitro-naphthalen2-Methyl-1-nitronaphthalene>Naphthalene, 2-Methyl-1-nitro-2-Methyl-1-nitronaphthalene,99%2-Methyl-1-nitronaphthalene, 99% 5GR2-Methyl-1-nitronaphthalene in methanol
4-05-00-01698 (Beilstein Handbook Reference)NITRO-2-METHYLNAPHTHALENE, 1-92538-34-6RefChem:88001212-917-5IZNWACYOILBFEG-UHFFFAOYSA-N881-03-8MFCD00003914

データベース識別子

CAS
881-03-8、92538-34-6
PubChem CID
13432
DTXSID
DTXSID2025761
ChEMBL
CHEMBL1452824
UNII
0IG2R1R9F7
EC Number
212-917-5
Nikkaji
J113.687I

物性

構造計算による物性

XLogP
3.4
極性表面積
45.8 Ų
水素結合供与体数
0
水素結合受容体数
2
回転可能結合数
0
重原子数
14

実験および物理化学的性質

SpringerMaterials Properties13C nuclear magnetic resonance spectrum
Solubilityless than 0.1 mg/mL at 64 °F (NTP, 1992)
Boiling Point370 °F at 20 mmHg (NTP, 1992)
Melting Point174 to 180 °F (NTP, 1992)
Physical Description1-nitro-2-methylnaphthalene is a yellow solid. (NTP, 1992)

物理化学的性質

融点
79 · 79-82 °C(lit.)
沸点
185 · 185-186 °C18 mm Hg(lit.)
比重(密度)
1.1963 · 1.1963 (rough estimate)
屈折率
1.49 · 1.4900 (estimate)
貯蔵温度
Keep in dark place,Sealed in dry,Room Temperature
外見
powder to crystal

化学的性質

化学的特性yellow to ochre crystalline powder

安全と法規制

GHS分類

GHS Classification · 4 件

Warning

H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P317, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 2 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Fire HazardsFlash point data are not available for this chemical, but it is probably combustible. (NTP, 1992)
Reactive GroupHydrocarbons, Aromatic
Reactivity Profile · 1 件

Aromatic nitro compounds, such as 1-NITRO-2-METHYLNAPHTHALENE, range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups. Stable under normal conditions. Protect from bases. (NTP, 1992)

Air and Water ReactionsInsoluble in water.
Hazard Classes and CategoriesAcute Tox. 4 (100%)

安全と保護具

Fire FightingFires involving this compound should be controlled using a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1 件

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1 件

SMALL SPILLS AND LEAKAGE: You should dampen the solid spill material with acetone, then transfer the dampened material to a suitable container. Use absorbent paper dampened with acetone to pick up any remaining material. Seal your contaminated clothing and the adsorbent paper in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with acetone followed by washing with a strong soap and water solution. Do not reenter the contaminate area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Personal Protective Equipment (PPE) · 1 件

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

安全データ

F
8
wgk
3
tsca
TSCA listed
rtecs
QJ9708200
hs_code
29042090
risk_code
36/37/38

化学と産業

用途と製造

General Manufacturing InformationNaphthalene, 2-methyl-1-nitro-: INACTIVE

応用分野

一般的な説明Yellow solid.

上流・下流製品情報

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