基本情報
- 標準SMILES
COCC1CO1- InChIKey
LKMJVFRMDSNFRT-UHFFFAOYSA-N- 分子式
- C4H8O2
- 平均分子量
- 88.11 g/mol
- 単同位体質量
- 88.0524295
概要
Methyl glycidyl ether is a clear colorless liquid. (NTP, 1992)
名称と識別子
- 優先名称
- 1,2-Epoxy-3-methoxypropane
- IUPAC
- 2-(methoxymethyl)oxirane
- 現地名
- グリシジルメチルエーテル
- 英語名
- GLYCIDYL METHYL ETHER
- 分子式
- C4H8O2
- 分子量
- 88.11
名称と別名
名称をさらに表示
データベース識別子
- CAS
930-37-0- PubChem CID
- 13589
- DTXSID
DTXSID9025613- UNII
- 87MK2KA66T
- EC Number
- 213-216-7
- Nikkaji
- J60.714B
物性
構造計算による物性
- XLogP
- -0.2
- 極性表面積
- 21.8 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 2
- 回転可能結合数
- 2
- 重原子数
- 6
- 形式電荷
- 0
- 複雑度
- 44.8
実験および物理化学的性質
Flash Point
less than 69 °F (NTP, 1992)
Flash point < 21 °C
Physical Description
Methyl glycidyl ether is a clear colorless liquid. (NTP, 1992)
Colorless liquid; [CAMEO]
物理化学的性質
- 沸点
- 110 °C · 110°C
- 比重(密度)
- 0 · 0,98 g/cm3
- 屈折率
- 1.408 · 1.4080-1.4140
- 闪点
- 24 °C · 24°C
- 貯蔵温度
- Refrigerator
- 溶解性
- クロロホルム(微量)、トルエン(微量)
- 外見
- 油
- 色
- 無色
- InChI
- InChI=1S/C4H8O2/c1-5-2-4-3-6-4/h4H,2-3H2,1H3
- InChIKey
- LKMJVFRMDSNFRT-UHFFFAOYSA-N
- SMILES
- O1CC1COC
- CAS データベース
- 930 · 930-37-0
- EPAの化学物質情報
- Methyl glycidyl ether (930-37-0)
安全と法規制
GHS分類
GHS Classification
Danger
H225 (75%): Highly Flammable liquid and vapor [Danger Flammable liquids]
P210, P233, P240, P241, P242, P243, P261, P262, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P316, P319, P321, P330, P332+P317, P337+P317, P361+P364, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 4 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Danger
H225: Highly Flammable liquid and vapor [Danger Flammable liquids]
危険有害性情報
Reactivity Profile
METHYL GLYCIDYL ETHER, an ether can act as a base. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.
Hazard Classes and Categories
Flam. Liq. 2 (75%)
Flammable liquids - Category 2
安全と保護具
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
Nonfire Spill Response
SMALL SPILLS AND LEAKAGE: If you should spill this chemical, use absorbent paper to pick up all liquid spill material. Seal the absorbent paper, as well as any of your clothing which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Wash any surfaces you may have contaminated with a strong soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.
Personal Protective Equipment (PPE)
RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)
毒性情報
Non-Human Toxicity Excerpts
...THEY ARE VERY IRRITATING TO EYES, SKIN, & RESPIRATORY TRACT. /GLYCIDYL ETHERS/
1,2-EPOXY-3-METHOXYPROPANE WAS MUTAGENIC IN KLEBSIELLA PNEUMONIAE.
TOPICAL APPLICATION OF 0.1 ML ALIQUOT OF 1,2-EPOXY-3-METHOXYPROPANE TO CLIPPED & DEPILATED BACKS OF GUINEA PIGS 4 TIMES IN 10 DAYS. AFTER 2 WK REST PERIOD, GUINEA PIGS WERE CHALLENGED ON THE CLIPPED FLANKS. TWO OF THE 49 GUINEA PIGS TESTED BECAME SENSITIZED.
安全データ
- tsca
- TSCA listed
- rtecs
- TZ3530000
- ridadr
- 3271
- hs_code
- 2909200090
- risk_code
- 10
- 化審法
- (2)-2425
- 消防法
- 危-4-2-III
- safety_code
- 16
- hazard_class
- 3.1
- packing_group
- II
- 有毒物質データの
- 930-37-0(Hazardous Substances Data)
化学と産業
用途と製造
Uses
Used as a research chemical; Not commercially produced in the US; [HSDB]
RESEARCH CHEMICAL
U.S. Exports
(1979) No Data
(1981) No Data
U.S. Imports
(1979) No Data
(1981) No Data
U.S. Production
(1979) NOT PRODUCED COMMERCIALLY IN U.S.
(1981) NOT PRODUCED COMMERCIALLY IN U.S.
応用分野
使用2-(Methoxymethyl)oxirane is used in the fixation of biological tissues or in collagen bioprosthetic fixation processes.
一般的な説明Clear colorless liquid.
上流・下流製品情報
上流原料
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