トリス(4-フルオロフェニル)ホスフィン

Tris(4-fluorophenyl)phosphine

HCID 140387CAS 18437-78-0

部分構造検索類似構造を探す

基本情報

標準SMILES: Fc1ccc(P(c2ccc(F)cc2)c2ccc(F)cc2)cc1
InChIKey: GEPJPYNDFSOARB-UHFFFAOYSA-N
分子式: C18H12F3P
平均分子量: 316.3 g/mol
単同位体質量: 316.06287187

名称と識別子

優先名称: Tris(4-fluorophenyl)phosphine
IUPAC: tris(4-fluorophenyl)phosphane
現地名: トリス(4-フルオロフェニル)ホスフィン
英語名: Tris(4-fluorophenyl)phosphine
分子式: C18H12F3P
分子量: 316.26

名称と別名

Tris(4-fluorophenyl)phosphinePhosphine, tris(4-fluorophenyl)-Phosphine, tris(p-fluorophenyl)-DTXSID80171565tri-(4-Fluorophenyl)phosphineNSC 158458RefChem:192107DTXCID7094056627-663-4GEPJPYNDFSOARB-UHFFFAOYSA-N18437-78-0tris(4-fluorophenyl)phosphane

名称をさらに表示

トリス(4-フルオロフェニル)フォスフィントリス(4-フルオロフェニル)ホスフィントリス(4‐フルオロフェニル)ホスフィントリス(P-フルオロフェニル)ホスフィントリス(p-フルオロフェニル)ホスフィン, 99%トリ(4-フルオロフェニル)ホスフィントリス(4-フルオロフェニル)ホスファンTris(4-fLTris(4-fluoropheTris(4-fluorophenyl)Tris(4-Flurophenyl)Phosphinetri(4-fluorophenyl)phosphinoTri-(p-fluorophenyl)phosphine

Tris(p-fluorophenyl)phosphineMFCD00013553TRI(4-FLUOROPHENYL)PHOSPHINEp(4-fc6h4)3C18H12F3PSCHEMBL196718tris (p-fluorophenyl)phosphineCS-W009423

データベース識別子

CAS: 18437-78-0
PubChem CID: 140387
DTXSID: DTXSID80171565
EC Number: 627-663-4
Nikkaji: J126.187H

物性

構造計算による物性

XLogP: 4.9
極性表面積: 0 Å²
水素結合供与体数: 0
水素結合受容体数: 3
回転可能結合数: 3
重原子数: 22
形式電荷: 0
複雑度: 275

物理化学的性質

融点: 79 · 79-83 °C(lit.)
沸点: 160 °C/0.1mmHg · 160°C/0.1mmHg(lit.)
貯蔵温度: Inert atmosphere,Room Temperature
外見: 結晶性粉末
色: 白色～わずかに黄色
水溶解度: 水に不溶。
BRN: 919838 · 919838
InChI: InChI=1S/C18H12F3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H
InChIKey: GEPJPYNDFSOARB-UHFFFAOYSA-N
SMILES: P(C1=CC=C(F)C=C1)(C1=CC=C(F)C=C1)C1=CC=C(F)C=C1
CAS データベース: 18437 · 18437-78-0(CAS DataBase Reference)

化学的性質

化学的特性white to light yellow crystal powde

安全と法規制

GHS分類

GHS Classification · 5 件

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (97.8%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 46 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Hazard Classes and CategoriesSkin Irrit. 2 (100%)；Eye Irrit. 2 (100%)；STOT SE 3 (97.8%)

安全データ

wgk: 3
hs_code: 29319090
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-36
hazard_class: IRRITANT
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3
ストレージクラス: 11 - Combustible Solids

化学と産業

応用分野 · 3 件

用途有機合成原料。

使用Tris(4-fluorophenyl)phosphine (TFPP) and tris(2,2,2- trifluoroethyl) phosphite (TTFP) were used as flame-retarding additives in Li-ion battery clectrolytes. Ligand for rhodium-catalyzed oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.

一般的な説明We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

調製方法

製造方法with 4-bromofluorobenzene, magnesium, and phosphorous (III) trichloride.3 Alternatively, reduction of tris(4-fluorophenyl)phosphine oxide with an iron catalyst.