CAS 34723-82-5 2-(Bromomethyl)tetrahydro-2H-pyran (HCID 141917)

基本情報

CAS: 34723-82-5
標準SMILES: BrCC1CCCCO1
InChIKey: MHNWCBOXPOLLIB-UHFFFAOYSA-N
分子式: C6H11BrO
平均分子量: 179.05 g/mol
単同位体質量: 177.99932707

名称と識別子

優先名称: 2-(Bromomethyl)tetrahydro-2H-pyran
IUPAC: 2-(bromomethyl)oxane
現地名: テトラヒドロ-2-(ブロモメチル)-2H-ピラン
英語名: 2-(BROMOMETHYL)TETRAHYDRO-2 H-PYRAN
分子式: C6H11BrO
分子量: 179.05

名称と別名

2-(Bromomethyl)tetrahydro-2H-pyran34723-82-52H-Pyran, 2-(bromomethyl)tetrahydro-9BYT763GMT2-(bromomethyl)tetrahydropyranUNII-9BYT763GMTNSC-167066DTXSID4022286Pyran, 2-(bromomethyl)tetrahydro-NSC 167066RefChem:84604DTXCID402286

名称をさらに表示

テトラヒドロ-2-(ブロモメチル)-2H-ピラン2-(ブロモメチル)テトラヒドロ-2H-ピラン2-(-ブロモメチル)テトラヒドロ-2H-ピラン2-(ブロモメチル)オキサンTETRAHYDRO-2 H-PYRAN-2-METHYL BROMIDE2-(Bromomethyl)tetrahydro-2H-pyran 98%2-(Bromomethyl)tetrahydro-2H-pyran ,98%2-(Bromomethyl)tetrahydro-2H-pyran - [B73609]

2-(BROMOMETHYL)TETRAHYDRO-2H-PYRAN, (+-)-628-186-4MHNWCBOXPOLLIB-UHFFFAOYSA-N2-(bromomethyl)oxane2-(BROMOMETHYL)TETRAHYDRO-2 H-PYRANMFCD00010116Tetrahydro-2H-pyran-2-methyl bromide2-Bromomethyl-tetrahydro-pyran

データベース識別子

CAS: 34723-82-5
PubChem CID: 141917
DTXSID: DTXSID4022286
UNII: 9BYT763GMT
EC Number: 628-186-4
Nikkaji: J150.068F

物性

構造計算による物性

XLogP: 1.8
極性表面積: 9.2 Å²
水素結合供与体数: 0
水素結合受容体数: 1
回転可能結合数: 1
重原子数: 8
形式電荷: 0
複雑度: 65.5

物理化学的性質

融点: 59 · −59-−58 °C(lit.)
沸点: 153 °C · 153 °C(lit.)
比重(密度): 1.397 g/mL · 1.397 g/mL at 25 °C(lit.)
屈折率: 20 · n20/D 1.489(lit.)
闪点: 149 °F · 149 °F
貯蔵温度: Store at room temperature
外見: liquid
InChI: 1S/C6H11BrO/c7-5-6-3-1-2-4-8-6/h6H,1-5H2
InChIKey: MHNWCBOXPOLLIB-UHFFFAOYSA-N
SMILES: BrCC1CCCCO1
CAS データベース: 34723 · 34723-82-5

化学的性質

化学的特性Colorless to yellow liquid

安全と法規制

GHS分類

GHS Classification · 4 件

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory Information2H-Pyran, 2-(bromomethyl)tetrahydro-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Hazard Classes and CategoriesSkin Irrit. 2 (100%)

安全データ

wgk: 3
hs_code: 29329990
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-36/37/39
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3
ストレージクラス: 10 - Combustible liquids

化学と産業

応用分野

使用2-(Bromomethyl)tetrahydro-2H-pyran has been used in the preparation of tellurated heterocycles, 2-[(2-thienyltelluro)methyl]tetrahydrofuran and [(2-thienyltelluro)methyl]tetrahydro-2H-pyran.

一般的な説明Cross-coupling reaction of 2-(bromomethyl)tetrahydro-2H-pyran with potassium heteroaryltrifluoroborates has been investigated.